Formation of the lithium alkylaluminium secondary amide [Me2Al{PhCH2}2Li.THF] by a methane elimination / amide insertion process

Armstrong, D.R. and Craig, F.J. and Kennedy, A.R. and Mulvey, R.E. (1998) Formation of the lithium alkylaluminium secondary amide [Me2Al{PhCH2}2Li.THF] by a methane elimination / amide insertion process. Journal of Organometallic Chemistry, 550 (1-2). pp. 355-358. ISSN 0022-328X

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Official URL: http://dx.doi.org/10.1016/S0022-328X(97)00549-4

Abstract

Synthesised by refluxing the amine adduct [Me3Al · (PhCH2)2NLi · HN(CH2Ph)2] in toluene/THF, the title compound has been structurally characterised by X-ray diffraction, and the methane elimination/amide insertion processes involved in its formation have been modelled theoretically through a series of ab initio MO calculations.

Creators(s):	Armstrong, D.R., Craig, F.J., Kennedy, A.R. ORCID: https://orcid.org/0000-0003-3652-6015 and Mulvey, R.E. ORCID: https://orcid.org/0000-0002-1015-2564;
Item type:	Article
ID code:	1300
Keywords:	Ab initio, X-ray diffraction, Heterobimetallics, Aluminium, Amide, Lithium, Chemistry, Materials Chemistry, Biochemistry, Organic Chemistry, Physical and Theoretical Chemistry, Inorganic Chemistry
Subjects:	Science > Chemistry
Department:	Faculty of Science > Pure and Applied Chemistry
Depositing user:	Catriona Mccallum
Date deposited:	26 Jun 2006
Last modified:	08 Jul 2020 00:30
URI:	https://strathprints.strath.ac.uk/id/eprint/1300
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