Formation of the lithium alkylaluminium secondary amide [Me2Al{PhCH2}2Li.THF] by a methane elimination / amide insertion process

Armstrong, D.R. and Craig, F.J. and Kennedy, A.R. and Mulvey, R.E. (1998) Formation of the lithium alkylaluminium secondary amide [Me2Al{PhCH2}2Li.THF] by a methane elimination / amide insertion process. Journal of Organometallic Chemistry, 550 (1-2). pp. 355-358. ISSN 0022-328X

Full text not available in this repository.Request a copy from the Strathclyde author

Abstract

Synthesised by refluxing the amine adduct [Me3Al · (PhCH2)2NLi · HN(CH2Ph)2] in toluene/THF, the title compound has been structurally characterised by X-ray diffraction, and the methane elimination/amide insertion processes involved in its formation have been modelled theoretically through a series of ab initio MO calculations.

ORCID iDs

Armstrong, D.R., Craig, F.J., Kennedy, A.R. ORCID logoORCID: https://orcid.org/0000-0003-3652-6015 and Mulvey, R.E. ORCID logoORCID: https://orcid.org/0000-0002-1015-2564;
  • Item type:Article
    ID code:1300
    Dates:
    Date
    Event
    27 April 1998
    Published
    Keywords:Ab initio, X-ray diffraction, Heterobimetallics, Aluminium, Amide, Lithium, Chemistry, Materials Chemistry, Biochemistry, Organic Chemistry, Physical and Theoretical Chemistry, Inorganic Chemistry
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Catriona Mccallum
    Date deposited:26 Jun 2006
    Last modified:20 Jan 2021 16:42
    URI:https://strathprints.strath.ac.uk/id/eprint/1300
CORE (COnnecting REpositories)