Alkoxide binding in inverse crown chemistry: rational synthesis of a series of composite alkali metal-magnesium-alkoxide-diisopropylamides

Drewette, K.J. and Henderson, K.W. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. and Rowlings, R.B. (2002) Alkoxide binding in inverse crown chemistry: rational synthesis of a series of composite alkali metal-magnesium-alkoxide-diisopropylamides. Chemical Communications (London), 2002 (11). pp. 1176-1177. ISSN 0009-241X (http://dx.doi.org/10.1039/b202549c)

Abstract

A series of composite lithium- or sodium-magnesium-alkoxide-diisopropylamides of general formula [{MMg[N(Pr-i)(2)](2)OR}(2)] (where M = Li, R = Oct(n); M = Na, R = Bu-n or Oct(n)), has been synthesised rationally by treating synergic amide mixtures with the appropriate alcohol.

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• Item metadata

  Item type:	Article
  ID code:	606
  Dates:	Date Event 3 May 2002 Published
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Mr Derek Boyle
  Date deposited:	28 Mar 2006
  Last modified:	08 Apr 2024 15:24
  URI:	https://strathprints.strath.ac.uk/id/eprint/606