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Open Access research with a European policy impact...

The Strathprints institutional repository is a digital archive of University of Strathclyde's Open Access research outputs. Strathprints provides access to thousands of Open Access research papers by Strathclyde researchers, including by researchers from the European Policies Research Centre (EPRC).

EPRC is a leading institute in Europe for comparative research on public policy, with a particular focus on regional development policies. Spanning 30 European countries, EPRC research programmes have a strong emphasis on applied research and knowledge exchange, including the provision of policy advice to EU institutions and national and sub-national government authorities throughout Europe.

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Synthesis and crystal and solution structures of the 1 : 1 TMEDA complex of lithium thiocyanate, (LiSCN·TMEDA)n[TMEDA = Me2N(CH2)2NMe2]: a polymeric solid with Li+ ions linked by bifunctional linear SCN– ligands

BARR, D and DOYLE, M J and Mulvey, Robert and RAITHBY, P R and SNAITH, R and WRIGHT, D S (1988) Synthesis and crystal and solution structures of the 1 : 1 TMEDA complex of lithium thiocyanate, (LiSCN·TMEDA)n[TMEDA = Me2N(CH2)2NMe2]: a polymeric solid with Li+ ions linked by bifunctional linear SCN– ligands. Journal of the Chemical Society, Chemical Communications (2). pp. 145-147. ISSN 0022-4936

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Abstract

The anhydrous complex (LiSCN·TMEDA)n(1)[TMEDA = Me2N(CH2)2NMe2] has been synthesised by a novel in situ route from solid NH4SCN and BunLi in TMEDA/hexane, and shown to have a polymeric chain crystal structure with Li–N[graphic omitted]CS Li repeat units; in hydrocarbon solvents, however, (1) adopts a dimeric, purely N–Li bridged structure.