Lithium-aluminate-catalyzed hydrophosphination applications

Pollard, Victoria A. and Young, Allan and McLellan, Ross and Kennedy, Alan R. and Tuttle, Tell and Mulvey, Robert E. (2019) Lithium-aluminate-catalyzed hydrophosphination applications. Angewandte Chemie International Edition, 58 (35). pp. 12291-12296. ISSN 1433-7851

[img]
Preview
 Text (Mulvey-etal-ACIE-2019-lithium-aluminate-catalyzed-hydrophosphination-applications)
Mulvey_etal_ACIE_2019_lithium_aluminate_catalyzed_hydrophosphination_applications.pdf
Final Published Version
License: Creative Commons Attribution 4.0 logo
Download (1MB)| Preview

    Abstract

    Synthesized, isolated, and characterized by X-ray crystallography and NMR spectroscopic studies, lithium phosphidoaluminate iBu3AlPPh2Li(THF)3 has been tested as a catalyst for hydrophosphination of alkynes, alkenes, and carbodiimides. Based on the collective evidence of stoichiometric reactions, NMR monitoring studies, kinetic analysis, and DFT calculations, a mechanism involving deprotonation, alkyne insertion and protonolysis is proposed for the [iBu3AlHLi]2 aluminate-catalyzed hydrophosphination of alkynes with diphenylphosphine. This study enhances further the development of transition metal free, atom economical homogeneous catalysis using common sustainable main group metals.

    Author(s):Pollard, Victoria A. ORCID logoORCID: https://orcid.org/0000-0002-9149-3458, Young, Allan ORCID logoORCID: https://orcid.org/0000-0002-1525-4703, McLellan, Ross ORCID logoORCID: https://orcid.org/0000-0001-9700-0258, Kennedy, Alan R. ORCID logoORCID: https://orcid.org/0000-0003-3652-6015, Tuttle, Tell and Mulvey, Robert E. ORCID logoORCID: https://orcid.org/0000-0002-1015-2564
    Item type:Article
    ID code:68689
    Keywords:aluminate, homogeneous catalysis, hydrophosphination, lithium, phosphine, Chemistry, Chemistry (miscellaneous)
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Pure Administrator
    Date deposited:02 Jul 2019 15:08
    Last modified:13 Nov 2019 04:48
    URI:https://strathprints.strath.ac.uk/id/eprint/68689
    Export data:
    CORE (COnnecting REpositories)