Mixed-metal sodium-magnesium macrocyclic amide chemistry: A template reaction for the site selective dideprotonation of arene molecules

Armstrong, D.R. and Kennedy, A.R. and Mulvey, R.E. and Rowlings, R.B. (1999) Mixed-metal sodium-magnesium macrocyclic amide chemistry: A template reaction for the site selective dideprotonation of arene molecules. Angewandte Chemie, 38 (1-2). pp. 131-133. ISSN 0044-8249 (http://dx.doi.org/10.1002/(SICI)1521-3773(19990115...)

Abstract

A remarkable pair of macrocyclic amides has been synthesized and crystallographically characterized; these consist of a twelve-membered (N6Na4Mg2)2+ cationic ring host with [C6H3(CH3)]2- or (C6H4)2- dianionic guests (see picture) derived from toluene and benzene, respectively.

ORCID iDs

Kennedy, A.R. ORCID: https://orcid.org/0000-0003-3652-6015

Mulvey, R.E. ORCID: https://orcid.org/0000-0002-1015-2564

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  Item type:	Article
  ID code:	1279
  Dates:	Date Event 15 January 1999 Published
  Keywords:	macrocyclic amides, crystallographically, toluene, benzene, Chemistry, Medicine(all)
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Users 45 not found.
  Date deposited:	23 Jun 2006
  Last modified:	19 May 2023 00:58
  URI:	https://strathprints.strath.ac.uk/id/eprint/1279