A novel heterometallic alkoxide: lithium-potassium tert-butoxide [((BuO)-O-t)(8)Li4K4]

Clegg, W and Drummond, A M and Liddle, S T and Mulvey, Robert and Robertson, A (1999) A novel heterometallic alkoxide: lithium-potassium tert-butoxide [((BuO)-O-t)(8)Li4K4]. Chemical Communications (16). pp. 1569-1570. ISSN 1359-7345

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Abstract

Synthesised from its homonuclear components in the presence of the Lewis base TMEDA, the title heteronuclear alkoxide crystallises in an unsolvated TMEDA-free form; its novel breastplate-like Li4K4O8 cage structure, which undergoes an exchange process in arene solution as determined by dynamic NMR spectroscopic studies, displays a planar K-4 arrangement in marked contrast to the tetrahedral K-4 arrangement found in homonuclear [((BuOK)-O-t)(4)].

Creators(s): Clegg, W, Drummond, A M, Liddle, S T, Mulvey, Robert ORCID logoORCID: https://orcid.org/0000-0002-1015-2564 and Robertson, A;
Item type:Article
ID code:38327
Keywords:solid state structure , metal alkoxides, complex structures, Chemistry, Materials Chemistry, Surfaces, Coatings and Films, Metals and Alloys, Ceramics and Composites, Chemistry(all), Catalysis, Electronic, Optical and Magnetic Materials
Subjects:Science > Chemistry
Department:Faculty of Science > Pure and Applied Chemistry
Depositing user: Pure Administrator
Date deposited:08 Mar 2012 14:12
Last modified:03 Apr 2020 00:54
URI:https://strathprints.strath.ac.uk/id/eprint/38327
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