A novel heterometallic alkoxide: lithium-potassium tert-butoxide [((BuO)-O-t)(8)Li4K4]
Clegg, W and Drummond, A M and Liddle, S T and Mulvey, Robert and Robertson, A (1999) A novel heterometallic alkoxide: lithium-potassium tert-butoxide [((BuO)-O-t)(8)Li4K4]. Chemical Communications (16). pp. 1569-1570. ISSN 1359-7345
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Abstract
Synthesised from its homonuclear components in the presence of the Lewis base TMEDA, the title heteronuclear alkoxide crystallises in an unsolvated TMEDA-free form; its novel breastplate-like Li4K4O8 cage structure, which undergoes an exchange process in arene solution as determined by dynamic NMR spectroscopic studies, displays a planar K-4 arrangement in marked contrast to the tetrahedral K-4 arrangement found in homonuclear [((BuOK)-O-t)(4)].
Creators(s): |
Clegg, W, Drummond, A M, Liddle, S T, Mulvey, Robert ![]() | Item type: | Article |
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ID code: | 38327 |
Keywords: | solid state structure , metal alkoxides, complex structures, Chemistry, Materials Chemistry, Surfaces, Coatings and Films, Metals and Alloys, Ceramics and Composites, Chemistry(all), Catalysis, Electronic, Optical and Magnetic Materials |
Subjects: | Science > Chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry |
Depositing user: | Pure Administrator |
Date deposited: | 08 Mar 2012 14:12 |
Last modified: | 20 Jan 2021 20:02 |
URI: | https://strathprints.strath.ac.uk/id/eprint/38327 |
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