Picture water droplets

Developing mathematical theories of the physical world: Open Access research on fluid dynamics from Strathclyde

Strathprints makes available Open Access scholarly outputs by Strathclyde's Department of Mathematics & Statistics, where continuum mechanics and industrial mathematics is a specialism. Such research seeks to understand fluid dynamics, among many other related areas such as liquid crystals and droplet evaporation.

The Department of Mathematics & Statistics also demonstrates expertise in population modelling & epidemiology, stochastic analysis, applied analysis and scientific computing. Access world leading mathematical and statistical Open Access research!

Explore all Strathclyde Open Access research...

A novel heterometallic alkoxide: lithium-potassium tert-butoxide [((BuO)-O-t)(8)Li4K4]

Clegg, W and Drummond, A M and Liddle, S T and Mulvey, Robert and Robertson, A (1999) A novel heterometallic alkoxide: lithium-potassium tert-butoxide [((BuO)-O-t)(8)Li4K4]. Chemical Communications (16). pp. 1569-1570. ISSN 1359-7345

Full text not available in this repository. Request a copy from the Strathclyde author

Abstract

Synthesised from its homonuclear components in the presence of the Lewis base TMEDA, the title heteronuclear alkoxide crystallises in an unsolvated TMEDA-free form; its novel breastplate-like Li4K4O8 cage structure, which undergoes an exchange process in arene solution as determined by dynamic NMR spectroscopic studies, displays a planar K-4 arrangement in marked contrast to the tetrahedral K-4 arrangement found in homonuclear [((BuOK)-O-t)(4)].