Regioselective solvation in a polymeric lithium amide : remarkable twisted ladder structure of [{[PhCH2N(H)Li]2•H2NCH2Ph}∞]

Kennedy, Alan R. and Mulvey, Robert E. and Robertson, Alan (1998) Regioselective solvation in a polymeric lithium amide : remarkable twisted ladder structure of [{[PhCH2N(H)Li]2•H2NCH2Ph}∞]. Chemical Communications, 1998 (1). pp. 89-90. ISSN 1359-7345

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Abstract

The hemi-benzylamine complex of lithium benzylamide exists in the crystal as an infinite, twisted-ladder structure of fused (NLi)2 rings; curiously, one edge of the ladder is solvated by benzylamine molecules, while the other is solvent-free.

Author(s):Kennedy, Alan R. ORCID logoORCID: https://orcid.org/0000-0003-3652-6015, Mulvey, Robert E. ORCID logoORCID: https://orcid.org/0000-0002-1015-2564 and Robertson, Alan
Item type:Article
ID code:1302
Keywords:crystal structures, polymeric lithium amide, MO, Chemistry, Materials Chemistry, Surfaces, Coatings and Films, Metals and Alloys, Ceramics and Composites, Chemistry(all), Catalysis, Electronic, Optical and Magnetic Materials
Subjects:Science > Chemistry
Department:Faculty of Science > Pure and Applied Chemistry
Depositing user: Catriona Mccallum
Date deposited:26 Jun 2006
Last modified:23 Jan 2020 01:28
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URI:https://strathprints.strath.ac.uk/id/eprint/1302
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