Crystallographic characterisation of binary alkali metal alkoxide magnesium bis(alkyl) mixtures: differential binding of Na+ and K+ to a common dinuclear diorganomagnesiate
Barnett, N.D.R. and Clegg, W. and Kennedy, A.R. and Mulvey, R.E. and Weatherstone, S. (2005) Crystallographic characterisation of binary alkali metal alkoxide magnesium bis(alkyl) mixtures: differential binding of Na+ and K+ to a common dinuclear diorganomagnesiate. Chemical Communications (London), 2005 (3). pp. 375-377. ISSN 0009-241X
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Relevant to mixtures studied in solution and utilised in styrene polymerisation but hitherto not characterised in the solid, two crystal structures of alkali metal alkoxide-magnesium bis(alkyl) co-complexes have been determined, revealing that in binding to the C2O tripodal face of a common organomagnesiate anion, Na+ prefers O-coordination, whereas K+ prefers C-coordination.
Creators(s): |
Barnett, N.D.R., Clegg, W., Kennedy, A.R. ![]() ![]() | Item type: | Article |
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ID code: | 644 |
Keywords: | heterobimetallic alkali, crystal-structure, inverse crown, potassium, chemistry, Chemistry, Chemistry(all) |
Subjects: | Science > Chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry Unknown Department |
Depositing user: | Mr Derek Boyle |
Date deposited: | 28 Mar 2006 |
Last modified: | 20 Jan 2021 17:00 |
Related URLs: | |
URI: | https://strathprints.strath.ac.uk/id/eprint/644 |
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