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Model structural types for rationalising stoichiometries and coordination numbers in lithium amidomagnesiates : syntheses and X-ray diffraction studies of [{Mg(NR2)2}2], [Li2Mg(NR2)4] and [LiMg(NR2)3·py](R = benzyl, py = pyridine)

Clegg, W. and Henderson, Kenneth W. and Mulvey, Robert and O'Neil, P.A. (1994) Model structural types for rationalising stoichiometries and coordination numbers in lithium amidomagnesiates : syntheses and X-ray diffraction studies of [{Mg(NR2)2}2], [Li2Mg(NR2)4] and [LiMg(NR2)3·py](R = benzyl, py = pyridine). Journal of the Chemical Society, Chemical Communications, 1994 (6). pp. 769-770. ISSN 0022-4936

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Abstract

Factors governing the intermetallic ratios and coordination geometries in lithium amidomagnesiates are discussed with reference to three model crystal structures containing the same (dibenzylamido) ligand, which remarkably reveal that an unsolvated lithium can induce coordination expansion about a magnesium centre.

Item type: Article
ID code: 38149
Keywords: crystal structure, aryl compounds, metal alkyl, complex, amide, Chemistry, Molecular Medicine
Subjects: Science > Chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Depositing user: Pure Administrator
Date deposited: 05 Mar 2012 14:04
Last modified: 03 Jan 2019 13:16
URI: https://strathprints.strath.ac.uk/id/eprint/38149
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