A polymeric solvent-free variant of a hydridomagnesium inverse crown

Graham, D.V. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. (2006) A polymeric solvent-free variant of a hydridomagnesium inverse crown. Acta Crystallographica Section C: Crystal Structure Communications, 62 (8). M366-M368. ISSN 0108-2701

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Official URL: http://dx.doi.org/10.1107/S0108270106025091

Abstract

A solvent-free agostically propagated polymeric variant of a previously reported hydride-containing inverse crown molecule has been prepared, namely tetra-mu(2)-diisopropylamido-di-mu(2)-hydrido-dimagnesium(II) disodium(I), [Mg2Na2H2(C6-H14N)(4)]. The asymmetric unit contains two crystallographically independent centrosymmetric molecules, each existing as a cationic eight-membered ring, with alternating metal and N atoms, which acts as a host towards two hydride anions. The metal amide rings are linked via Na (.) (.) (.) C agostic interactions to produce one-dimensional polymeric chains propagating along the crystallographic b direction.

Creators(s):	Graham, D.V., Kennedy, A.R. ORCID: https://orcid.org/0000-0003-3652-6015, Mulvey, R.E. ORCID: https://orcid.org/0000-0002-1015-2564 and O'Hara, C.T. ORCID: https://orcid.org/0000-0002-1691-1568;
Item type:	Article
ID code:	17229
Keywords:	alkali metal magnesium, chemistry, hydride, Chemistry, Biochemistry, Genetics and Molecular Biology(all)
Subjects:	Science > Chemistry
Department:	Faculty of Science > Pure and Applied Chemistry
Depositing user:	Strathprints Administrator
Date deposited:	07 Apr 2010 15:50
Last modified:	20 Jan 2021 18:28
URI:	https://strathprints.strath.ac.uk/id/eprint/17229
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