Expanding the Scope of Lithium Coordination Chemistry by Placing Sodium Nearby: A Mixed Lithium-Sodium Benzyl Compound Having TMEDA-Chelated Li+ Cations in an Unprecedented Tetrameric Environment
Baker, Daniel R. and Clegg, William and Horsburgh, Lynne and Mulvey, Robert (1994) Expanding the Scope of Lithium Coordination Chemistry by Placing Sodium Nearby: A Mixed Lithium-Sodium Benzyl Compound Having TMEDA-Chelated Li+ Cations in an Unprecedented Tetrameric Environment. Organometallics, 13 (11). pp. 4170-4172. ISSN 0276-7333
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Abstract
Mixed-alkali-metal metalation of toluene in the presence of TMEDA produces the benzyl complex [(PhCH(2))(4)Li2-xNa2+x(TMEDA)(4)], which has an octagonal ring structure that, in. spite of the 4-fold aggregation, contains Li+ cations complexed by bidentate TMEDA, a situation normally sterically forbidden in, homometallic lithium tetramers.
Creators(s): |
Baker, Daniel R., Clegg, William, Horsburgh, Lynne and Mulvey, Robert ![]() | Item type: | Article |
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ID code: | 38837 |
Keywords: | structural characterisitcs, crystal structure, alkali, Chemistry, Organic Chemistry, Physical and Theoretical Chemistry, Inorganic Chemistry |
Subjects: | Science > Chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry |
Depositing user: | Pure Administrator |
Date deposited: | 30 Mar 2012 11:51 |
Last modified: | 01 Jan 2021 10:15 |
URI: | https://strathprints.strath.ac.uk/id/eprint/38837 |
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