Browse by Author or Creator

Article

Rajasekharan Nair, Rajeev and Moore, Dean and Chalmers, Kirsten and Wallace, Dawn and Diamond, Louise M. and Darby, Lisa and Armstrong, David and Reglinski, John and Spicer, Mark (2013) S-alkylation of soft scorpionates. Chemistry - A European Journal, 19 (7). pp. 2487-2495. ISSN 0947-6539

Armstrong, David R. and Brammer, Elanor and Cadenbach, Thomas and Hevia, Eva and Kennedy, Alan R. (2013) Co-complexation syntheses, structural characterization, and DFT studies of a novel series of polymeric alkali-metal tetraorganogallates. Organometallics, 32 (2). pp. 480-489. ISSN 0276-7333

Rajasekharan Nair, Rajeev and Marckwordt, Annemarie and Lutta, Samuel and Schwalbe, Matthias and Biernat, Anne and Armstrong, David and Watson, Allan and Kennedy, Alan and Reglinski, John and Spicer, Mark (2013) Soft Scorpionate anions as platforms for novel heterocycles. Chemistry - A European Journal. ISSN 0947-6539 (In Press)

Sassmannshausen, Joerg and Klett, Jan and Kennedy, Alan R. and Parkinson, John A. and Armstrong, David (2013) Taming the shrew : [TMEDALi-Zn(C2H4)(2)L] as a model compound for anionic ethene polymerisation. New Journal of Chemistry, 37 (2). pp. 494-501. ISSN 1144-0546

Armstrong, David R. and Kennedy, Alan R. and Mulvey, Robert E. and Robertson, Stuart D. (2013) A hetero-alkali-metal version of the utility amide LDA : lithium-potassium diisopropylamide. Dalton Transactions, 42 (10). pp. 3704-3711. ISSN 1477-9226

Armstrong, David R. and Kennedy, Alan and Mulvey, Robert E. and Parkinson, John A. and Robertson, Stuart D. (2012) Opening the black box of mixed-metal TMP metallating reagents : direct cadmation or lithium-cadmium transmetallation? Chemical Science, 3 (9). pp. 2700-2707. ISSN 2041-6520

Armstrong, D. R. and Balloch, L. and Crawford, J. J. and Fleming, B. J. and Hogg, L. M. and Kennedy, A. R. and Klett, J. and Mulvey, R. E. and O'Hara, C. T. and Orr, S. A. and Robertson, Stuart (2012) Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)center dot Na(mu-TMP)(mu-Bu-t)Zn(Bu-t)] towards TEMPO and chalcone. Chemical Communications, 48 (10). pp. 1541-1543. ISSN 1359-7345

Mulvey, Robert and Armstrong, David R. and Conway, Ben and Crosbie, Elaine and Kennedy, Alan and Robertson, Stuart (2011) Structurally powered synergic 2,2,6,6-tetramethylpiperidine bimetallics: new reflections through lithium-mediated ortho aluminations. Inorganic chemistry, 50 (24). pp. 12241-12251. ISSN 0020-1669

Armstrong, David R. and Balloch, Liam and Hevia, Eva and Kennedy, Alan R. and Mulvey, Robert E. and O'Hara, Charles T. and Robertson, Stuart D. (2011) Meta-metallation of N,N-dimethylaniline: contrasting direct sodium-mediated zincation with indirect sodiation-dialkylzinc co-complexation. Beilstein Journal of Organic Chemistry, 7. pp. 1234-1248. ISSN 1860-5397

Armstrong, David R. and Kennedy, Alan R. and Mulvey, Robert E. and Robertson, Stuart D. (2011) Developing a hetero-alkali-metal chemistry of 2,2,6,6-tetramethylpiperidide (TMP): stoichiometric and structural diversity within a series of lithium/sodium, lithium/potassium and sodium/potassium TMP compounds. Chemistry - A European Journal, 17 (32). pp. 8820-8831. ISSN 0947-6539

Armstrong, David R. and Clegg, William and Garcia-Alvarez, Pablo and Kennedy, Alan R. and McCall, Matthew D. and Russo, Luca and Hevia, Eva (2011) Expanding Mg-Zn hybrid chemistry : inorganic salt effects in addition reactions of organozinc reagents to trifluoroacetophenone and the implications for a synergistic lithium-magnesium-zinc activation. Chemistry - A European Journal, 17 (30). pp. 8333-8341. ISSN 0947-6539

Armstrong, David R. and Garcia-Alvarez, Pablo and Kennedy, Alan R. and Mulvey, Robert E. and Robertson, Stuart D. (2011) Molecular structures of THF-solvated alkali-metal 2,2,6,6-tetramethylpiperidides finally revealed: x-ray crystallographic, DFT, and NMR (including DOSY) spectroscopic studies. Chemistry - A European Journal, 17 (24). pp. 6725-6730. ISSN 0947-6539

Armstrong, David R. and Clegg, William and Garcia-Alvarez, Pablo and McCall, Matthew D. and Nuttall, Lorraine and Kennedy, Alan R. and Russo, Luca and Hevia, Eva (2011) Shedding new light on ZnCl2-mediated addition reactions of Grignard reagents to ketones : structural authentication of key intermediates and diffusion-ordered NMR studies. Chemistry - A European Journal, 17 (16). pp. 4470-4479. ISSN 0947-6539

Armstrong, David R. and Blair, Victoria L. and Clegg, William and Dale, Sophie H. and Garcia-Alvarez, Joaquin and Honeyman, Gordon W. and Hevia, Eva and Mulvey, Robert E. and Russo, Luca (2010) Structural basis for regioisomerization in the alkali-metal-mediated zincation (AMMZn) of trifluoromethyl benzene by isolation of kinetic and thermodynamic intermediates. Journal of the American Chemical Society, 132 (27). pp. 9480-9487. ISSN 0002-7863

Armstrong, D.R. and Garcia-Alvarez, P. and Kennedy, A.R. and Mulvey, R.E. and Parkinson, J.A. (2010) Diisopropylamide and TMP turbo-grignard reagents : a structural rationale for their contrasting reactivities. Angewandte Chemie, 122 (18). 3253–3256. ISSN 0044-8249

Wallace, Dawn and Quinn, Edward John and Armstrong, David and Reglinski, J. and Spicer, M.D. and Smith, W.E. (2010) Surface science of soft scorpionates. Inorganic chemistry, 49 (4). pp. 1420-1427. ISSN 0020-1669

Mustapha, Abdullahi and Reglinski, J. and Kennedy, Alan R. and Armstrong, D.R. and Sassmannshausen, Jorg and Murrie, Mark (2010) Multidentate ligands for the synthesis of multi-metallic complexes. 2. Formation of a planar Cu4OH motif. Inorganic chemistry, 49 (12). pp. 5350-5352. ISSN 0020-1669

Armstrong, D.R. and Balloch, L. and Clegg, William and Dale, S.H. and Garcia-Alvarez, P. and Hevia, E. and Hogg, L.M. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, Charles (2009) Synergic synthesis of benzannulated zincabicyclic complexes, alpha-zincated n ylides, through sodium-TMEDA-mediated zincation of a haloarene. Angewandte Chemie, 48 (46). pp. 8675-8678. ISSN 0044-8249

Kennedy, A.R. and Andrikopoulos, P.C. and Arlin, J.B. and Armstrong, D.R. and Duxbury, N. and Graham, D.V. and Kirkhouse, J.B.A. (2009) Supramolecular structure in s-block metal complexes of sulfonated monoazo dyes : discrepant packing and bonding behavior of ortho-sulfonated azo dyes. Chemistry - A European Journal, 15 (37). pp. 9494-9504. ISSN 0947-6539

Trotter, K.D. and Reglinski, J. and Robertson, K. and Forgie, J.C. and Parkinson, J.A. and Kennedy, A.R. and Armstrong, D.R. and Sowden, R.J. and Spickett, C.M. (2009) Structural studies of trans-N2S2 copper macrocycles. Inorganica Chimica Acta, 362 (11). pp. 4065-4072. ISSN 0020-1693

Stevenson, Ross and Stokes, Robert J. and MacMillan, Donna and Armstrong, David and Faulds, Karen and Wadsworth, Roger and Kununthur, Suma and Suckling, Colin J. and Graham, Duncan (2009) In situ detection of pterins by SERS. Analyst, 134. pp. 1561-1564. ISSN 0003-2654

Armstrong, D.R. and Garcia-Alvarez, J. and Graham, D.V. and Honeyman, G.W. and Hevia, E. and Kennedy, A.R. and Mulvey, R.E. (2009) Synthetic and structural insights into the zincation of toluene: direct synergic ring metallation versus indirect nonsynergic lateral metallation. Chemistry - A European Journal, 15 (15). pp. 3800-3807. ISSN 0947-6539

Armstrong, D.R. and Dougan, C. and Graham, D.V. and Hevia, E. and Kennedy, A.R. (2008) Synthesis and structural elucidation of alkyl, amido, and mixed. alkyl-amido "highly-coordinated" zincates. Organometallics, 27 (23). pp. 6063-6070. ISSN 0276-7333

Armstrong, D.R. and Drummond, A.M. and Balloch, L. and Graham, D.V. and Hevia, E. and Kennedy, A.R. (2008) Metalation of 2,4,6-trimethylacetophenone using organozinc reagents: the role of the base in determining composition and structure of the developing enolate. Organometallics, 27 (22). pp. 5860-5866. ISSN 0276-7333

Stokes, Robert J. and Ingram, Andrew and Gallagher, Jane and Armstrong, David R. and Smith, W. Ewen and Graham, Duncan (2008) Squaraines as unique reporters for SERRS multiplexing. Chemical Communications (London) (5). pp. 567-569. ISSN 0009-241X

Armstrong, D.R. and Herd, E. and Graham, D.V. and Hevia, E. and Kennedy, A.R. and Clegg, W. and Russo, L. (2008) Synthesis and structural elucidation of solvent-free and solvated lithium dimethyl (HMDS) zincates. Dalton Transactions (10). pp. 1323-1330. ISSN 1472-7773

Armstrong, D.R. and Clegg, W. and Dale, S.H. and Garcia-Alvarez, Joaquin and Harrington, R.W. and Hevia, E. and Honeyman, G.W. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. (2008) Transamination chemistry of sodium TMP-zincate: synthesis and crystal structure of a chiral amidozincate. Chemical Communications (London) (2). pp. 187-189. ISSN 0009-241X

Armstrong, D.R. and Graham, D.V. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. (2008) A structural and computational study of synthetically important alkali-metal/tetramethylpiperidide (tmp) amine solvates. Chemistry - A European Journal, 14 (26). pp. 8025-8034. ISSN 0947-6539

Schwalbe, Matthias and Andrikopoulos, P.C. and Armstrong, David R. and Reglinski, J. and Spicer, M.D. (2007) Structural and theoretical insights into metal-scorpionate ligand complexes. European Journal of Inorganic Chemistry, 2007 (10). pp. 1351-1360. ISSN 1434-1948

Andrikopoulos, Prokopis C. and Armstrong, D.R. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. and Rowlings, Rene and Weatherstone, Susan (2007) Synthesis and structural characterisation of mixed alkalimetal-magnesium mixed ligand alkyl-amido ate complexes. Inorganica Chimica Acta, 360 (4). pp. 1370-1375. ISSN 0020-1693

Armstrong, D.R. and Clegg, William and Dale, S.H. and Graham, D.V. and Hevia, E. and Hogg, L.M. and Honeyman, G.W. and Kennedy, A.R. and Mulvey, R.E. (2007) Dizincation and dimagnesiation of benzene using alkali-metal-mediated metallation. Chemical Communications (London) (6). pp. 598-600. ISSN 0009-241X

Andrikopoulos, P.C. and McCarney, K.M. and Armstrong, D.R. and Littleford, R.E. and Graham, D. and Smith, W.E. (2006) A density functional theory and resonance Raman study of a benzotriazole dye used in surface enhanced resonance Raman scattering. Journal of Molecular Structure, 789 (1-3). pp. 59-70. ISSN 0022-2860

Mulvey, R.E. and Armstrong, David R. and Clegg, W. and Hevia, E. and Dale, S.H. and Hogg, L.M. and Honeyman, G.W. (2006) Directed meta-metalation using alkali-metal-mediated zincation. Angewandte Chemie, 45. pp. 3775-3778. ISSN 1521-3757

Hevia, E. and Armstrong, David R. and Kennedy, A. and Mulvey, R.E. (2006) Synergic para-directed-monometalation ofcby using alkali-metal-mediated magnesiation. Organometallics, 25. pp. 2415-2418. ISSN 0276-7333

Andrikopoulos, P.C. and Armstrong, D.R. and Barley, H.R.L. and Clegg, W. and Dale, S.H. and Hevia, E. and Honeyman, G.W. and Kennedy, A.R. and Mulvey, R.E. (2005) Sodium dialkyl-amidozincates: Alkyl or amido bases? An experimental and theoretical case study. Journal of the American Chemical Society, 127 (17). pp. 6184-6185. ISSN 0002-7863

Andrikopoulos, P.C. and Armstrong, D.R. and Graham, D.V. and Hevia, E. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. and Talmard, C. (2005) Selective meta-deprotonation of toluene by using alkali-metal-mediated magnesiation. Angewandte Chemie, 44 (22). pp. 3459-3462. ISSN 0044-8249

Andrikopoulos, P.C. and Armstrong, D.R. and Hevia, E. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. (2005) Stoichiometrically-controlled reactivity and supramolecular storage of butylmagnesiate anions. Chemical Communications (London), 2005 (9). pp. 1131-1133. ISSN 0009-241X

Andrikopoulos, P.C. and Armstrong, D.R. and Clegg, W. and Gilfillan, C.J. and Hevia, E. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. and Parkinson, J.A. and Tooke, D.M. (2004) A homologous series of regioselectively tetradeprotonated group 8 metallocenes: New inverse crown ring compounds synthesized via a mixed sodium-magnesium tris(diisopropylamide) synergic base. Journal of the American Chemical Society, 126 (37). pp. 11612-11620. ISSN 0002-7863

Andrikopoulos, P.C. and Armstrong, D.R. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. and Rowlings, R.B. (2003) Synthesis, structure and theoretical studies of the hydrido inverse crown [K2Mg2(NiPr2)(4)(mu-H)(2)center dot(toluene)(2)]: a rare example of a molecular magnesium hydride with a Mg-(mu-H)(2)-Mg double bridge. European Journal of Inorganic Chemistry, 2003 (18). pp. 3354-3362. ISSN 1434-1948

Armstrong, D.R. and Forbes, G.C. and Mulvey, R.E. and Clegg, W. and Tooke, D.M. (2002) An unexpected transamination of bis[bis(trimethylsilyl)amido]zinc with dibenzylamine to form bis( dibenzylamido)zinc: structural studies by NMR spectroscopy, X-ray crystallography and theoretical calculations. Dalton Transactions, 2002 (8). pp. 1656-1661. ISSN 1472-7773

Andrews, Philip C. and Armstrong, David R. and Raston, Colin L. and Roberts, Brett A. and Skelton, Brian W. and White, Allan H. (2001) Alkali metal and magnesium enamides from metallation of the alkyl ligands [(2-Pyr)(SiMe3)CH2 and [6-Me-(2-Pyr)(SiMe3)CH2] : a solid state and ab initio study. Journal of the Chemical Society, Dalton Transactions, 1472 (7). pp. 996-1006.

Armstrong, D.R. and Clegg, W. and Mulvey, R.E. and Rowlings, R.B. (2001) Synthesis and crystal structure of the new heteroleptic magnesium bis(amide) [{Mg[mu-N(H)Ph][N(SiMe3)(2)]center dot THF}(2)], and density functional MO calculations on model systems. Journal of the Chemical Society, Dalton Transactions, 2001 (4). pp. 409-413. ISSN 0300-9246

Armstrong, D.R. and Henderson, K.W. and Little, I. and Jenny, C. and Kennedy, A.R. and McKeown, A.E. and Mulvey, R.E. (2000) Zirconocene ketimides: Synthesis, structural characterization, ethylene polymerization activity, and ab initio computational studies. Organometallics, 19 (21). pp. 4369-4375. ISSN 0276-7333

Armstrong, D.R. and Henderson, K.W. and Kennedy, A.R. and Kerr, W.J. and Mair, F.S. and Moir, J.H. and Moran, P.H. and Snaith, R. (1999) Structural Studies of the Chiral Lithium Amides [{PhC(H)Me}2NLi] and [PhCH2{PhC(H)Me}NLi.THF Derived from a-Methybenzylamine. Journal of the Chemical Society, Dalton Transactions, 1999 (22). pp. 4063-4068. ISSN 0300-9246

Armstrong, D.R. and Kennedy, A.R. and Mulvey, R.E. and Rowlings, R.B. (1999) Mixed-metal sodium-magnesium macrocyclic amide chemistry: A template reaction for the site selective dideprotonation of arene molecules. Angewandte Chemie, 38 (1-2). pp. 131-133. ISSN 0044-8249

Armstrong, D.R. and Craig, F.J. and Kennedy, A.R. and Mulvey, R.E. (1998) Formation of the lithium alkylaluminium secondary amide [Me2Al{PhCH2}2Li.THF] by a methane elimination / amide insertion process. Journal of Organometallic Chemistry, 550 (1-2). pp. 355-358. ISSN 0022-328X

Armstrong, D.R. and Craig, F.J. and Kennedy, A.R. and Mulvey, R.E. (1996) Crystal structure of a representative mixed adduct of trimethylaluminium and a lithium amide and a theoretical MO study on model systems. Chemische berichte, 129. pp. 1293-1300. ISSN 0009-2940

Book Section

Ackermann, F. and Eden, C. (2005) Using causal mapping to support information systems development: some considerations. In: Causal Mapping for Research in Information Technology. Hershey, United States, pp. 263-283. ISBN 1591403979