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Jump to: 2012 | 2011 | 2010 | 2009 | 2008 | 2007 | 2006 | 2005 | 2004 | 2003 | 2002 | 2000 | 1999
Number of items: 94.

2012

Mills, Andrew and Lawrie, Katherine and Bardin, Julie and Apedaile, Alistair and Skinner, Graham A. and O'Rourke, Christopher (2012) An O2 smart plastic film for packaging. Analyst, 137 (1). pp. 106-112. ISSN 0003-2654

2011

Mills, A. and Tommons, C. and Bailey, R. T. and Crilly, P. and Tedford, M. C. (2011) Thin-film oxygen sensors using a luminescent polynuclear gold(I) complex. Analytica Chimica Acta, 702 (2). pp. 269-273. ISSN 0003-2670

Mills, A. and Hazafy, D. and Lawrie, K. (2011) Novel photocatalyst-based colourimetric indicator for oxygen. Catalysis Today, 161 (1). pp. 59-63. ISSN 0920-5861

Hazafy, David and Salvia, Marie-Virginie and Mills, Andrew and Hutchings, Michael G. and Evstigneev, Maxim P. and Parkinson, John A. (2011) NMR analysis of Nile Blue (C. I. Basic Blue 12) and Thionine (C. I. 52000) in solution. Dyes and Pigments, 88 (3). pp. 315-325. ISSN 0143-7208

Agbani, E. O. and Coats, P. and Mills, A. and Wadsworth, R. M. (2011) Peroxynitrite stimulates pulmonary artery endothelial and smooth muscle cell proliferation : Involvement of ERK and PKC. Pulmonary Pharmacology and Therapeutics, 24 (1). pp. 100-109.

Fleming, Scott and Mills, Andrew and Tuttle, Tell (2011) Predicting the UV-Vis Spectra of Oxazine Dyes. Beilstein Journal of Organic Chemistry, 7. pp. 432-441. ISSN 1860-5397

Kundu, S. and Kafizas, A. and Hyett, G. and Mills, A. and Darr, J. A. and Parkin, I. P. (2011) An investigation into the effect of thickness of titanium dioxide and gold-silver nanoparticle titanium dioxide composite thin-films on photocatalytic activity and photo-induced oxygen production in a sacrificial system. Journal of Materials Chemistry, 21 (19). pp. 6854-6863. ISSN 0959-9428

Mills, A. and Skinner, G. A. (2011) A novel 'fizziness' indicator. Analyst, 136 (5). pp. 894-896. ISSN 0003-2654

2010

Mills, Andrew and Katafias, Anna and Chatłas, Janusz and Impert, Olga and Kita, Przemysław and Madej, Edyta and Topolskia, Adrian and Wrzeszcz, Grzegorz (2010) Reactivity difference between protolytic forms of some macrocyclic chromium(III) complexes in ligand substitution and electron transfer processes. Inorganica Chimica Acta, 363 (11). pp. 2346-2356. ISSN 0020-1693

Mills, Andrew and Skinner, Graham A. and Grosshans, Pauline (2010) Intelligent pigments and plastics for CO2 detection. Journal of Materials Chemistry, 20. pp. 5008-5010. ISSN 0959-9428

Mills, A. and Duckmanton, Paul and Reglinski, J. (2010) A simple, novel method for preparing an effective water oxidation catalyst. Chemical Communications (London), 46 (14). pp. 2397-2398. ISSN 0009-241X

Mills, A. and Hazafy, D. and Parkinson, J. and Tuttle, T. and Hutchings, Michael G. (2010) Effect of alkali on methylene blue (C.I. basic blue 9) and other thiazine dyes. Dyes and Pigments, 88 (2). pp. 149-155.

Mills, A. (2010) Water-based colourimetric optical indicators for the detection of carbon dioxide. Analyst, 135. pp. 1912-1917. ISSN 0003-2654

Mills, A. (2010) A comprehensive aerosol spray method for the rapid photocatalytic grid area analysis of semiconductor photocatalyst thin films. Analytica Chimica Acta, 663. pp. 69-76. ISSN 0003-2670

2009

Mills, A. and Hazafy, D. and Parkinson, J.A. and Tuttle, T. and Hutchings, M.G. (2009) Comment on "solvent effect on the electronic spectra of azine dyes under alkaline condition". Journal of Physical Chemistry A, 113 (34). pp. 9575-9576. ISSN 1089-5639

Mills, A. and Sheik, M. and O'Rourke, C. and McFarlane, M. (2009) Adsorption and photocatalysed destruction of cationic and anionic dyes on mesoporous titania films: reactions at the air-solid interface. Applied Catalysis B: Environmental, 89 (1-2). pp. 189-195. ISSN 0926-3373

Mills, A. and Cusick, A. and Hepburn, J. (2009) The kinetics of semiconductor photocatalysis in activity-indicator films. Journal of Advanced Oxidation Technologies, 12 (2). pp. 152-157. ISSN 1203-8407

Kafizas, A. and Adriaens, D. and Mills, A. and Parkin, I.P. (2009) Simple method for the rapid simultaneous screening of photocatalytic activity over multiple positions of self-cleaning films. Physical Chemistry Chemical Physics, 11 (37). pp. 8367-8375. ISSN 1463-9084

Mills, A. and Hepburn, J. and McFarlane, M. (2009) A novel, fast-responding, indicator ink for thin film photocatalytic surfaces. ACS Applied Materials and Interfaces, 1 (6). pp. 1163-1165. ISSN 1944-8252

Zita, J. and Krysa, J. and Mills, A. (2009) Correlation of oxidative and reductive dye bleaching on TiO2 photocatalyst films. Journal of Photochemistry and Photobiology A: Chemistry, 203 (2-3). pp. 119-124. ISSN 1010-6030

Mills, A. and Grosshans, P. and Snadden, E. (2009) Hydrogen peroxide vapour indicator. Sensors and Actuators B: Chemical, 136 (2). pp. 458-463. ISSN 0925-4005

Mills, A. and Hazafy, D. (2009) Nanocrystalline sno2-based, uvb-activated, colourimetric oxygen indicator. Sensors and Actuators B: Chemical, 136 (2). pp. 344-349. ISSN 0925-4005

Mills, A. and McDiarmid, K. and McFarlane, M. and Grosshans, P. (2009) Flagging up sunburn: a printable, multicomponent, uv-indicator that warns of the approach of erythema. Chemical Communications (London) (11). pp. 1345-1346. ISSN 0009-241X

Mills, A. and Grosshans, P. and McFarlane, M. (2009) Uv dosimeters based on neotetrazolium chloride. Journal of Photochemistry and Photobiology A: Chemistry, 201 (2-3). pp. 136-141. ISSN 1010-6030

Mills, A. and Lawrie, K. and McFarlane, M. (2009) Blue bottle light: lecture demonstrations of homogeneous and heterogeneous photo-induced electron transfer reactions. Photochemical and Photobiological Sciences, 8 (3). pp. 421-425. ISSN 1474-905X

Mills, A. (2009) Optical sensors for carbon dioxide and their applications. In: NATO Advanced Study Institute on Sensors for Environment, Health and Security: Advanced Materials and Technologies, 2007-09-16 - 2007-09-27.

Mills, A.; (2009) Oxygen indicators in food packaging. In: NATO Science for Peace and Security Series C: Environmental Security. Springer, pp. 371-388. ISBN 1874-6519

Mills, A. and Grosshans, P. (2009) Uv dosimeter based on dichloroindophenol and tin(iv) oxide. Analyst, 134 (5). pp. 845-850. ISSN 0003-2654

2008

Howe, Russell F. and Robertson, Peter K.J. and Mills, Andrew (2008) Preface to the special issue on selected papers from the Second International Conference on Semiconductor Photochemistry SP-2. International Journal of Photoenergy, 2008. 258561. ISSN 1110-662X

Mills, A. and McGrady, M. (2008) A study of new photocatalyst indicator inks. Journal of Photochemistry and Photobiology A: Chemistry, 193 (2-3). pp. 228-236. ISSN 1010-6030

Mills, Andrew and Tommons, Cheryl and Bailey, Raymond T. and Tedford, M. Catriona and Crilly, Peter J. (2008) UV-activated luminescence/colourimetric O2 indicator. International Journal of Photoenergy. 547301. ISSN 1110-662X

Mills, Andrew and McGrady, Mark and Wang, Jishun and Hepburn, James (2008) A rapid method of assessing the photocatalytic activity of thin TiO2 films using an ink based on the redox dye 2,6-dichloroindophenol. International Journal of Photoenergy, 2008. 504945. ISSN 1110-662X

Mills, A. and Hazafy, D. (2008) A solvent-based intelligence ink for oxygen. Analyst, 133 (2). pp. 213-218. ISSN 0003-2654

Mills, Andrew and Crow, Matthew (2008) A study of factors that change the wettability of titania films. International Journal of Photoenergy. 470670. ISSN 1110-662X

2007

Mills, A. and McFarlane, Michael (2007) Current and possible future methods of assessing the activities of photocatalyst films. Catalysis Today, 129 (1-2). pp. 22-28.

Evans, P. and Mantke, S. and Mills, A. and Sheel, D.W. (2007) A comparative study of three techniques for determining photocatalytic activity. Journal of Photochemistry and Photobiology A: Chemistry, 188 (2-3). pp. 387-391. ISSN 1010-6030

Mills, A. and Crow, M. (2007) In situ, continuous monitoring of the photoinduced superhydrophilic effect: influence of uv-type and ambient atmospheric and droplet composition. Journal of Physical Chemistry C, 111 (16). pp. 6009-6016.

Mills, A. and Wang, Jishun S. and Crow, M. and Taglioni, G. and Novella, L. (2007) Novel low-temperature photocatalytic titania films produced by plasma-assisted reactive dc magnetron sputtering. Journal of Photochemistry and Photobiology A: Chemistry, 187 (2-3). pp. 370-376. ISSN 1010-6030

Mills, A. and Crow, M. and Wang, Jishun and Parkin, I.P. and Boscher, N. (2007) Photocatalytic oxidation of deposited sulfur and gaseous sulfur dioxide by TiO2 films. Journal of Physical Chemistry C, 111 (14). pp. 5520-5525.

Katafias, A. and Kita, P. and Wrzeszcz, G. and Mills, A. (2007) Kinetics of the methylene blue oxidation by cerium(iv) in sulphuric acid solutions. Transition Metal Chemistry, 32 (1). pp. 31-37. ISSN 0340-4285

Mills, A. and Tommons, Cheryl and Bailey, R.T. and Tedford, M.Catriona and Crilly, Peter J. (2007) Reversible, fluorescence-based optical sensor for hydrogen peroxide. Analyst, 132 (6). pp. 566-571. ISSN 0003-2654

2006

Peiro, Ana M. and Colombo, Claudia and Doyle, Gerry and Nelson, Jenny and Mills, Andrew and Durrant, James R. (2006) Photochemical reduction of oxygen adsorbed to nanocrystalline tio2 films: a transient absorption and oxygen scavenging study of different tio2 preparations. Journal of Physical Chemistry B, 110 (46). pp. 23255-23263. ISSN 1520-6106

Mills, A. and Wang, Jishun S. and Ollis, David F. (2006) Dependence of the kinetics of liquid-phase photocatalyzed reactions on oxygen concentration and light intensity. Journal of Catalysis, 243 (1). pp. 1-6. ISSN 0021-9517

Mills, A. and McFarlane, Michael and Schneider, Stefan (2006) A viologen-based UV indicator and dosimeter. Analytical and Bioanalytical Chemistry, 386 (2). pp. 299-305. ISSN 1618-2642

Mills, A. and Wang, Jishun S. (2006) Simultaneous monitoring of the destruction of stearic acid and generation of carbon dioxide by self-cleaning semiconductor photocatalytic films. Journal of Photochemistry and Photobiology A: Chemistry, 182 (2). pp. 181-186. ISSN 1010-6030

Mills, Andrew and Wang, Jishun and McGrady, Mark (2006) Method of rapid assessment of photocatalytic activities of self-cleaning films. Journal of Physical Chemistry B, 110 (37). pp. 18324-18331. ISSN 1520-6106

Mills, A. and Wang, Jishun S. and Crow, M. (2006) Photocatalytic oxidation of soot by P25 TiO(2) films. Chemosphere, 64 (6). pp. 1032-1035. ISSN 1879-1298

Mills, Andrew and Wang, Jishun and Ollis, David F. (2006) Kinetics of liquid phase semiconductor photoassisted reactions : supporting observations for a pseudo-steady-state model. Journal of Physical Chemistry B, 110 (29). pp. 14386-14390. ISSN 1520-6106

Mills, A. and Doyle, Gerry and Peiro, Ana M. and Durrant, James R. (2006) Demonstration of a novel, flexible, photocatalytic oxygen-scavenging polymer film. Journal of Photochemistry and Photobiology A: Chemistry, 177 (2-3). pp. 328-331. ISSN 1010-6030

Mills, A. and Tommons, Cheryl and Bailey, R.T. and Tedford, M.Catriona and Crilly, Peter J. (2006) Luminescence temperature sensing using poly(vinyl alcohol)-encapsulated ru(bpy)(3)(2+) films. Analyst, 131 (4). pp. 495-500. ISSN 0003-2654

2005

Mills, A. and Hill, G. and Crow, M. and Hodgen, S. (2005) Thick titania films for semiconductor photocatalysis. Journal of Applied Electrochemistry, 35 (7). pp. 641-653. ISSN 0021-891X

Lee, S-K. and Sheridan, M. and Mills, A. (2005) Novel UV-activated colorimetric oxygen indicator. Chemistry of Materials, 17 (10). pp. 2744-2751. ISSN 0897-4756

Mills, Andrew and Lee, Soo-Keun and Sheridan, Martin (2005) Development of a novel UV indicator and dosimeter film. Analyst, 130 (7). pp. 1046-1051. ISSN 0003-2654

Mills, A. and Hodgen, S.; Geddes, C.D. and Lakowicz, J.R., eds. (2005) Fluorescent carbon dioxide indicators. In: Advanced Concepts in Fluorescence Sensing. Topics in Fluorescence Spectroscopy, 9 (9). Springer, Berlin, Germany, pp. 119-162. ISBN 9780387233345

Mills, A. and Peiro, A.M. and Doyle, G.T. and Durrant, J.R. (2005) Freestanding polymer-metal oxide nanocomposite films for light-driven oxygen scavenging. Advanced Materials, 17 (19). pp. 2365-2368. ISSN 1521-4095

Mills, A. (2005) Oxygen indicators and intelligent inks for packaging food. Chemical Society Reviews, 34 (12). pp. 1003-1011. ISSN 0306-0012

Mills, A. and Hodgen, S. and Lee, S-K. (2005) Self-cleaning titania films: an overview of direct, lateral and remote photo-oxidation processes. Research on Chemical Intermediates, 31 (4-6). pp. 295-308. ISSN 0922-6168

Mills, A. and Lee, S-K. and Wang, J. and Simonsen, M. (2005) An intelligence ink for photocatalytic films. Chemical Communications (London), 2005 (21). pp. 2721-2723. ISSN 0009-241X

2004

Chatlas, J. and Impert, O. and Katafias, A. and Kita, P. and Wrzeszcz, G. and Eriksen, J. and Monsted, O. and Mills, A. (2004) Kinetics and mechanism of a macrocyclic chromium(III) complex oxidation to chromium(IV) by hexacyanoferrate(III) in strongly alkaline media. Transition Metal Chemistry, 29 (6). pp. 634-643. ISSN 0340-4285

Mills, A. and Hill, G. and Stewart, M. and Graham, D. and Smith, W.E. and Hodgen, S. and Halfpenny, P.J. and Faulds, K. and Robertson, P. (2004) Characterization of novel Ag on TiO2 films for surface-enhanced Raman scattering. Applied Spectroscopy, 58 (8). pp. 922-928. ISSN 0003-7028

Mills, Andrew and Valenzuela, Miguel A. (2004) The photo-oxidation of water by sodium persulfate, and other electron acceptors, sensitised by TiO2. Journal of Photochemistry and Photobiology A: Chemistry, 165 (1-3). pp. 25-34. ISSN 1010-6030

Mills, A. and Velenzuela, M. (2004) Photo-oxidation of water sensitized by TiO2 and WO3 in presence of different electron acceptors. Revista Mexicana de Fisica, 50 (3). pp. 287-296. ISSN 0035-001X

O'Neill, S. and Parkin, I.P. and Clark, R.J.H. and Mills, A. and Elliott, N. (2004) Photocatalytically active gamma-WO3 films from the atmospheric pressure CVD of WOCl4 with ethyl acetate or ethanol. Chemical Vapor Deposition, 10 (3). pp. 136-141. ISSN 0948-1907

Lee, Soo-Keun and Mills, Andrew (2004) Detoxification of water by semiconductor photocatalysis. Journal of Industrial and Engineering Chemistry, 10 (2). pp. 173-187. ISSN 1226-086X

Xiao, L. and Green, A.N.M. and Haque, S.A. and Mills, A. and Durrant, J.R. (2004) Light-driven oxygen scavenging by titania/polymer nanocomposite films. Journal of Photochemistry and Photobiology A: Chemistry, 162 (2-3). pp. 253-259. ISSN 1010-6030

Lee, Soo-Keun and McIntyre, Sharon and Mills, Andrew (2004) Visible illustration of the direct, lateral and remote photocatalytic destruction of soot by titania. Journal of Photochemistry and Photobiology A: Chemistry, 162 (1). pp. 203-206. ISSN 1010-6030

Mills, A. and Lee, S.K.; Parkins, S., ed. (2004) Semiconductor photocatalysis. In: Advanced Oxidation Processes for Water and Wastewater Treatment. IWA Publishing, London, UK, pp. 137-166. ISBN 1843390175

Mills, Andrew and Valenzuela, Miguel A. (2004) Semiconductores y fotocatálisis. Materiales Avanzados, 2. pp. 19-22.

Lee, Soo-Keun and Mills, Andrew and Lepre, Anne (2004) An intelligence ink for oxygen. Chemical Communications (London), 2004 (17). pp. 1912-1913. ISSN 0009-241X

2003

Lee, Soo-Keun and Mills, Andrew (2003) Luminescence of leuco-thiazine dyes. Journal of Fluorescence, 13 (5). pp. 375-377. ISSN 1053-0509

Mills, Andrew and Lepre, Anne and Elliott, Nicholas and Bhopal, Sharan and Parkin, Ivan P. and O'Neill, S.A. (2003) Characterisation of the photocatalyst Pilkington Activ (TM): a reference film photocatalyst? Journal of Photochemistry and Photobiology A: Chemistry, 160 (3). pp. 213-224. ISSN 1010-6030

Mills, Andrew and Hill, George and Bhopal, Sharan and Parkin, Ivan P. and O'Neill, Shane (2003) Thick titanium dioxide films for semiconductor photocatalysis. Journal of Photochemistry and Photobiology A: Chemistry, 160 (3). pp. 185-194. ISSN 1010-6030

Lee, Soo-Keun and Robertson, Peter K.J. and Mills, Andrew and McStay, Daniel and Elliott, N. and McPhail, Donald (2003) The alteration of the structural properties and photocatalytic activity of TiO2 following exposure to non-linear irradiation sources. Applied Catalysis B: Environmental, 44 (2). pp. 173-184. ISSN 0926-3373

Mills, A. (2003) Modelling the reponse features of optical sensors for oxygen: an overview. Proceedings of SPIE the International Society for Optical Engineering, 3856. pp. 232-242. ISSN 0277-786X

Lee, S.K. and Mills, A. (2003) Platinum and palladium in semiconductor photocatalytic systems. Platinum Metals Review, 47 (2). pp. 61-72. ISSN 0032-1400

Mills, A. and Lee, Soo-Keun and Lepre, Anne (2003) Photodecomposition of ozone sensitised by a film of titanium dioxide on glass. Journal of Photochemistry and Photobiology A: Chemistry, 155 (1-3). pp. 199-205. ISSN 1010-6030

O'Neill, S.A. and Clark, R.J.H. and Parkin, I.P. and Elliott, N. and Mills, A. (2003) Anatase thin films on glass from the chemical vapor deposition of titanium(IV) chloride and ethyl acetate. Chemistry of Materials, 15 (1). pp. 46-50. ISSN 0897-4756

Mills, A. and Lee, S.K. (2003) Platinum group metals and their oxides in semiconductor photosensitisation. Platinum Metals Review, 47 (1). pp. 2-12. ISSN 0032-1400

Rampaul, A. and Parkin, I.P. and O'Neill, S.A. and DeSouza, J. and Mills, A. and Elliott, N. (2003) Titania and tungsten doped titania thin films on glass: active photocatalysts. Polyhedron, 22 (1). pp. 35-44. ISSN 0277-5387

Mills, Andrew and Seth, Alison and Peters, Gavin (2003) Alkaline hydrolysis of trinitrotoluene, TNT. Physical Chemistry Chemical Physics, 5 (18). pp. 3921-3927. ISSN 1463-9084

O'Neill, S.A. and Parkin, I.P. and Clark, R.J.H. and Mills, A. and Elliott, N. (2003) Atmospheric pressure chemical vapour deposition of thin films of Nb2O5 on glass. Journal of Materials Chemistry, 13 (12). pp. 2952-2956. ISSN 0959-9428

O'Neill, S.A. and Parkin, I.P. and Clark, R.J.H. and Elliott, N. and Mills, A. (2003) Atmospheric pressure chemical vapour deposition of titanium dioxide coatings on glass. Journal of Materials Chemistry, 13 (1). pp. 56-60. ISSN 0959-9428

Impert, Olga and Katafias, A. and Kita, Przemyslaw and Mills, Andrew and Pietkiewiez-Graczyk, Aleksandra and Wrzeszcz, Grzegorz (2003) Kinetics and mechanism of a fast leuco-Methylene Blue oxidation by copper(II)-halide species in acidic aqueous media. Dalton Transactions, 2003 (3). pp. 348-353. ISSN 1472-7773

Lee, Soo-Keun and Mills, Andrew (2003) Novel photochemistry of leuco-Methylene Blue. Chemical Communications (London), 2003 (18). pp. 2366-2367. ISSN 0009-241X

Mills, A. and Elliott, Nicholas and Hill, George and Fallis, David and Durrant, James R. and Willis, Richard L. (2003) Preparation and characterisation of novel thick sol-gel titania film photocatalysts. Photochemical and Photobiological Sciences, 2 (5). pp. 591-596. ISSN 1474-905X

Sanderson, K.D. and Mills, A. and Hurst, S. and Lepre, A. and McKittrick, T. and Rimmer, D. and Ye, L. (2003) The use of titanium dioxide coatings deposited by APCVD on glass substrates to provide a dual action self cleaning. In: 46th Annual Society of Vacuum Coaters Technical Conference, 2003-05-03 - 2003-05-08.

2002

Mills, A. and Lee, S. and Lepre, A. and Parkin, I.P. and O'Neill, S.A. (2002) Spectral and photocatalytic characteristics of TiO2CVD films on quartz. Photochemical and Photobiological Sciences, 1 (11). pp. 865-868. ISSN 1474-905X

Mills, Andrew and Lee, Soo-Keun (2002) A web-based overview of semiconductor photochemistry-based current commercial applications. Journal of Photochemistry and Photobiology A: Chemistry, 152 (1-3). pp. 233-247. ISSN 1010-6030

Mills, A. and Elliott, N. and Parkin, I.P. and O'Neill, S.A. and Clark, R.J. (2002) Novel TiO2 CVD films for semiconductor photocatalysis. Journal of Photochemistry and Photobiology A: Chemistry, 151 (1-3). pp. 171-179. ISSN 1010-6030

Mills, A. and Robertson, P. (2002) Special issue: sp-1 first international conference on semiconductor photochemistry University of Strathclyde, Glasgow, july 2001 - preface. Journal of Photochemistry and Photobiology A: Chemistry, 148 (1-3). pp. 1-3. ISSN 1010-6030

2000

Hutchings, Michael G. and Mills, Andrew (2000) Additivity of substituent effects on the visible absorption spectra of some heteroarylazo compounds: the influence of solvent. Dyes and Pigments, 47 (1-2). pp. 23-31. ISSN 0143-7208

Saurez, M.F. and Mills, A. and Egdell, R.G. and Compton, R.G. (2000) Anodic stripping voltammetry with photochemical preconcentration at nanocrystalline TiO2 films: detection of Ag+ and Hg2+. Electroanalysis, 12 (6). pp. 413-419. ISSN 1040-0397

Mills, A. and Eaton, K. (2000) Optical sensors for carbon dioxide: an overview of sensing strategies past and present. Quimica Analitica, 19 (Supple). pp. 75-86. ISSN 0212-0569

1999

Mills, A. and Wang, J.S. (1999) Photobleaching of methylene blue sensitised by tio2: an ambiguous system? Journal of Photochemistry and Photobiology A: Chemistry, 127 (1-3). pp. 123-134. ISSN 1010-6030

This list was generated on Sat Dec 21 11:33:23 2024 GMT.