Photocatalytically active gamma-WO3 films from the atmospheric pressure CVD of WOCl4 with ethyl acetate or ethanol
O'Neill, S. and Parkin, I.P. and Clark, R.J.H. and Mills, A. and Elliott, N. (2004) Photocatalytically active gamma-WO3 films from the atmospheric pressure CVD of WOCl4 with ethyl acetate or ethanol. Chemical Vapor Deposition, 10 (3). pp. 136-141. ISSN 0948-1907
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Communication: Coatings Of Yellow gamma-WO3 are deposited on glass by APCVD of WOCl4 and either ethanol or ethylacetate at 350-450degreesC. The yellow films show significant photoactivity for the destruction of stearic acid, and photoinduced superhydrophilicity. Preparation of blue reduced WO2.92 films from the same reaction at higher substrate temperatures of 500-600degreesC (Figure) is also found to be possible. These films show no photoactivity, but can be converted into the fully stoichiometric photoactive form simply by heating in air.
Creators(s): | O'Neill, S., Parkin, I.P., Clark, R.J.H., Mills, A. and Elliott, N.; | Item type: | Article |
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ID code: | 456 |
Keywords: | OXIDE THIN-FILMS, CHEMICAL-VAPOR-DEPOSITION, SEMICONDUCTOR PHOTOCATALYSIS, WO3, OXIDATION, TIO2, Chemistry, Physics, Chemistry(all), Surfaces and Interfaces, Process Chemistry and Technology |
Subjects: | Science > Chemistry Science > Physics |
Department: | Faculty of Science > Pure and Applied Chemistry |
Depositing user: | Mr Derek Boyle |
Date deposited: | 09 Mar 2006 |
Last modified: | 05 Mar 2021 04:09 |
URI: | https://strathprints.strath.ac.uk/id/eprint/456 |
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