40Ar/39Ar age of the Rotoiti Breccia and Rotoehu Ash, Okataina Volcanic Complex, New Zealand, and identification of heterogeneously distributed excess 40Ar in supercooled crystals

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Flude, Stephanie and Storey, Michael (2016) 40Ar/39Ar age of the Rotoiti Breccia and Rotoehu Ash, Okataina Volcanic Complex, New Zealand, and identification of heterogeneously distributed excess 40Ar in supercooled crystals. Quaternary Geochronology, 33. pp. 13-23. ISSN 1871-1014 (https://doi.org/10.1016/j.quageo.2016.01.002)

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Abstract

Co-magmatic granitoid clasts erupted as part of the Rotoiti Ignimbrite (Rotoehu Tephra) contain euhedral K-feldspar and biotite crystals that protrude into miarolytic cavities and show textural evidence for growth in super-cooled conditions and are thus interpreted as growing during eruption. 40Ar/39Ar stepped heating experiments on single K-feldspar crystals reveal the presence of heterogeneously distributed excess 40Ar, preferentially released at lower temperature steps (most likely from fluid/melt inclusions), which cannot reliably be characterised by, or corrected for using isotope correlation diagrams due to mixing between three reservoirs of 40Ar (radiogenic, atmospheric and excess). This excess 40Ar component is common, but not ubiquitous, and an age population unmixing algorithm applied to single-crystal fusion data identifies a younger group of K-feldspar and biotite crystals that appear to be largely unaffected by excess 40Ar. This population gives a statistically robust weighted mean age of 47.4 ± 1.5 ka (1σ, n = 13) and an indistinguishable inverse isochron age of 50 ± 3 ka for this historically difficult to date eruption. The weighted mean age is significantly younger than previous age estimates of the Rotoiti eruption obtained by K/Ar and 40Ar/39Ar dating of bracketing lavas, but is indistinguishable from recent 14C and (U-Th)/He dates and estimates based on orbital tuning and sedimentation rates constrained by 14C ages.

ORCID iDs

Flude, Stephanie ORCID logoORCID: https://orcid.org/0000-0002-0511-0116 and Storey, Michael;
  • Item type:Article
    ID code:83832
    Dates:
    Date
    Event
    1 June 2016
    Published
    4 January 2016
    Accepted
    Notes:Funding Information: Colin Wilson, Roger Briggs, Bruce Houghton and Bill Davis are thanked for their guidance during fieldwork in New Zealand, which was carried out by MS during tenure of a 1-year fellowship at the University of Waikato. Quadlab is funded by a grant to MS from the Villum Foundation . This manuscript benefitted from comments and discussion by reviewers Andy Calvert and an anonymous reviewer, and Editor Paul Renne. Publisher Copyright: © 2016 Elsevier B.V.
    Subjects:Science > Geology
    Department:Faculty of Engineering > Civil and Environmental Engineering
    Depositing user: Pure Administrator
    Date deposited:26 Jan 2023 09:09
    Last modified:02 Dec 2024 01:28
    Related URLs:
    URI:https://strathprints.strath.ac.uk/id/eprint/83832
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