Heavier alkali-metal gallates as platforms for accessing functionalized abnormal NHC carbene-gallium complexes

Uzelac, Marina and Kennedy, Alan R. and Hernán-Gómez, Alberto and Fuentes, M. Ángeles and Hevia, Eva (2016) Heavier alkali-metal gallates as platforms for accessing functionalized abnormal NHC carbene-gallium complexes. Zeitschrift fur Anorganische und Allgemeine Chemie, 642 (22). pp. 1241-1244. ISSN 1521-3749 (https://doi.org/10.1002/zaac.201600310)

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Abstract

By sequentially treating the unsaturated carbene IPr (IPr = 1,3-bis-(2,6-diisopropylphenyl)imidazol-2-ylidene) with heavier alkali-metal alkyls NaR or KR (R = CH2SiMe3) and GaR3, novel heteroleptic gallates 1 and 2 have been prepared. Incorporating anionic NHC ligands, these bimetallic complexes react selectively with electrophilles to afford neutral abnormal NHC Ga complexes under mild conditions.

ORCID iDs

Uzelac, Marina ORCID logoORCID: https://orcid.org/0000-0002-5060-7017, Kennedy, Alan R. ORCID logoORCID: https://orcid.org/0000-0003-3652-6015, Hernán-Gómez, Alberto ORCID logoORCID: https://orcid.org/0000-0001-8150-7249, Fuentes, M. Ángeles and Hevia, Eva ORCID logoORCID: https://orcid.org/0000-0002-3998-7506;
  • Item type:Article
    ID code:59256
    Dates:
    Date
    Event
    16 November 2016
    Published
    28 September 2016
    Published Online
    12 September 2016
    Accepted
    Notes:This is the peer reviewed version of the following article: Uzelac, M., Kennedy, A. R., Hernán-Gómez, A., Fuentes, M. Á., & Hevia, E. (2016). Heavier alkali-metal gallates as platforms for accessing functionalized abnormal NHC carbene-gallium complexes. Zeitschrift fur Anorganische und Allgemeine Chemie, 642(22), 1241-1244, which has been published in final form at https://dx.doi.org/10.1002/zaac.201600310. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Pure Administrator
    Date deposited:04 Jan 2017 14:56
    Last modified:11 Nov 2024 11:35
    Related URLs:
    URI:https://strathprints.strath.ac.uk/id/eprint/59256
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