Towards energetically viable asymmetric deprotonations : selectivity at more elevated temperatures with C2-symmetric magnesium bisamides

Bennie, Linsey Sarah and Kerr, William and Middleditch, Michael and Watson, Allan (2011) Towards energetically viable asymmetric deprotonations : selectivity at more elevated temperatures with C2-symmetric magnesium bisamides. Chemical Communications (London), 47 (8). pp. 2264-2266. ISSN 0009-241X (https://doi.org/10.1039/c0cc04939e)

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Abstract

A novel chiral magnesium bisamide has enabled the development of effective asymmetric deprotonation protocols at substantially more elevated temperatures. This new, structurally simple, C2-symmetric magnesium complex displays excellent levels of asymmetric efficiency and energy reduction in the synthesis of enantioenriched enol silanes

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• Item metadata

  Item type:	Article
  ID code:	29177
  Dates:	Date Event 2011 Published
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	07 Mar 2011 23:27
  Last modified:	09 Apr 2024 08:11
  URI:	https://strathprints.strath.ac.uk/id/eprint/29177