Towards energetically viable asymmetric deprotonations : selectivity at more elevated temperatures with C2-symmetric magnesium bisamides

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Bennie, Linsey Sarah and Kerr, William and Middleditch, Michael and Watson, Allan (2011) Towards energetically viable asymmetric deprotonations : selectivity at more elevated temperatures with C2-symmetric magnesium bisamides. Chemical Communications (London), 47 (8). pp. 2264-2266. ISSN 0009-241X (https://doi.org/10.1039/c0cc04939e)

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Abstract

A novel chiral magnesium bisamide has enabled the development of effective asymmetric deprotonation protocols at substantially more elevated temperatures. This new, structurally simple, C2-symmetric magnesium complex displays excellent levels of asymmetric efficiency and energy reduction in the synthesis of enantioenriched enol silanes

ORCID iDs

Bennie, Linsey Sarah, Kerr, William ORCID logoORCID: https://orcid.org/0000-0002-1332-785X, Middleditch, Michael and Watson, Allan;
CORE (COnnecting REpositories)