Hydrogen-related 3.8 eV UV luminescence in α-Ga2O3

Nicol, D. and Oshima, Y. and Roberts, J. W. and Penman, L. and Cameron, D. and Chalker, P. R. and Martin, R. W. and Massabuau, F. C.-P. (2023) Hydrogen-related 3.8 eV UV luminescence in α-Ga2O3. Applied Physics Letters, 122 (6). 062102. ISSN 0003-6951 (https://doi.org/10.1063/5.0135103)

[thumbnail of Nicol-etal-APL-2023-Hydrogen-related-3-8-eV-UV-luminescence]
Preview
Text. Filename: Nicol_etal_APL_2023_Hydrogen_related_3_8_eV_UV_luminescence.pdf
Final Published Version
License: Creative Commons Attribution 4.0 logo

Download (927kB)| Preview

Abstract

Temperature-dependent photoluminescence was used to investigate the impact of H on the optical properties of α-Ga2O3 films grown by halide vapor phase epitaxy. An additional UV luminescence line centered at 3.8 eV is observed at low temperatures, which strongly correlates with the concentration of H in the films. This luminescence line is assigned to donor–acceptor pair recombination involving an H-related shallow donor and H-decorated Ga vacancy (VGa-nH) as the acceptor, where n = 1, 2, 3. Previous reports have already suggested the impact of H on the electrical properties of Ga2O3, and the present study shows its clear impact on the optical properties of α-Ga2O3.