The interplay of quantum confinement and hydrogenation in amorphous silicon quantum dots

Askari, Sadegh and Svrcek, Vladmir and Maguire, Paul and Mariotti, Davide (2015) The interplay of quantum confinement and hydrogenation in amorphous silicon quantum dots. Advanced Materials, 27 (48). pp. 8011-8016. ISSN 0935-9648 (https://doi.org/10.1002/adma.201503013)

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Abstract

Hydrogenation in amorphous silicon quantum dots (QDs) has a dramatic impact on the corresponding optical properties and band energy structure, leading to a quantum-confined composite material with unique characteristics. The synthesis of a-Si:H QDs is demonstrated with an atmospheric-pressure plasma process, which allows for accurate control of a highly chemically reactive non-equilibrium environment with temperatures well below the crystallization temperature of Si QDs.

ORCID iDs

Askari, Sadegh, Svrcek, Vladmir, Maguire, Paul and Mariotti, Davide ORCID logoORCID: https://orcid.org/0000-0003-1504-4383;