Selective phase growth and precise-layer control in MoTe2

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Fraser, James P. and Masaityte, Liudvika and Zhang, Jingyi and Laing, Stacey and Moreno-López, Juan Carlos and McKenzie, Adam F. and McGlynn, Jessica C. and Panchal, Vishal and Graham, Duncan and Kazakova, Olga and Pichler, Thomas and MacLaren, Donald A. and Moran, David A. J. and Ganin, Alexey Y. (2020) Selective phase growth and precise-layer control in MoTe2. Communications Materials, 1. 48. ISSN 2662-4443 (https://doi.org/10.1038/s43246-020-00048-4)

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Abstract

Minor structural changes in transition metal dichalcogenides can have dramatic effects on their electronic properties. This makes the quest for key parameters that enable a selective choice between the competing metallic and semiconducting phases in the 2D MoTe2 system compelling. Herein, we report the optimal conditions at which the choice of the initial seed layer dictates the type of crystal structure of atomically-thin MoTe2 films grown by chemical vapour deposition (CVD). When Mo metal is used as a seed layer, semiconducting 2H-MoTe2 is the only product. Conversely, MoO3 leads to the preferential growth of metallic 1T-MoTe2. The control over phase growth allows for simultaneous deposition of both 2H-MoTe2 and 1T '-MoTe2 phases on a single substrate during one CVD reaction. Furthermore, Rhodamine 6G dye can be detected using few-layered 1T '-MoTe2 films down to 5 nM concentration, demonstrating surface enhanced Raman spectroscopy (SERS) with sensitivity several orders of magnitude higher than for bulk 1T '-MoTe2.

ORCID iDs

Fraser, James P., Masaityte, Liudvika, Zhang, Jingyi, Laing, Stacey ORCID logoORCID: https://orcid.org/0000-0001-5781-349X, Moreno-López, Juan Carlos, McKenzie, Adam F., McGlynn, Jessica C., Panchal, Vishal, Graham, Duncan ORCID logoORCID: https://orcid.org/0000-0002-6079-2105, Kazakova, Olga, Pichler, Thomas, MacLaren, Donald A., Moran, David A. J. and Ganin, Alexey Y.;
CORE (COnnecting REpositories)