Evidence of single electron transfer from the enolate anion of an N,N'-dialkyldiketopiperazine additive in BHAS coupling reactions

Emery, Katie J. and Tuttle, Tell and Murphy, John A. (2017) Evidence of single electron transfer from the enolate anion of an N,N'-dialkyldiketopiperazine additive in BHAS coupling reactions. Organic and Biomolecular Chemistry, 15 (41). pp. 8810-8819. ISSN 1477-0520 (https://doi.org/10.1039/c7ob02209c)

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Abstract

A designed N,N'-dialkyldiketopiperazine (DKP) provides evidence for the role of DKP additives as initiators that act by electron transfer in base-induced homolytic aromatic substitution reactions, involving coupling of haloarenes to arenes.

  • Item type:Article
    ID code:63619
    Dates:
    Date
    Event
    25 October 2017
    Published
    5 October 2017
    Published Online
    5 October 2017
    Accepted
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Pure Administrator
    Date deposited:05 Apr 2018 09:52
    Last modified:17 Apr 2024 00:29
    URI:https://strathprints.strath.ac.uk/id/eprint/63619
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