Lithium diamidodihydridoaluminates : bimetallic cooperativity in catalytic hydroboration and metallation applications

Pollard, Victoria A. and Orr, Samantha A. and McLellan, Ross and Kennedy, Alan R. and Hevia, Eva and Mulvey, Robert E. (2018) Lithium diamidodihydridoaluminates : bimetallic cooperativity in catalytic hydroboration and metallation applications. Chemical Communications, 54 (10). pp. 1233-1236. ISSN 1359-7345 (https://doi.org/10.1039/C7CC08214B)

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Abstract

Cooperativity between the Li and Al centres is implicated in catalytic hydroboration reactions of aldehydes and ketones with pinacolborane via heteroleptic lithium diamidodihydridoaluminates. In addition to implementing hydroalumination, these versatile heteroleptic ates can also perform as amido bases as illustrated with an acidic triazole.

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• Item metadata

  Item type:	Article
  ID code:	62520
  Dates:	Date Event 4 February 2018 Published 16 January 2018 Published Online 29 November 2017 Accepted
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	05 Dec 2017 11:47
  Last modified:	08 Apr 2024 23:39
  Related URLs:	Journal or Publication
  URI:	https://strathprints.strath.ac.uk/id/eprint/62520