Regiospecific synthesis of N2-aryl 1,2,3-triazoles from 2,5-disubstituted tetrazoles via photochemically generated nitrile imine intermediates

Stewart, Sam and Harris, Robert and Jamieson, Craig (2014) Regiospecific synthesis of N2-aryl 1,2,3-triazoles from 2,5-disubstituted tetrazoles via photochemically generated nitrile imine intermediates. Synlett, 25 (17). pp. 2480-2484. ISSN 0936-5214 (https://doi.org/10.1055/s-0034-1379010)

Preview

PDF. Filename: Stewart_etal_Synlett_2015_Regiospecific_synthesis_of_N2_aryl.pdf Accepted Author Manuscript Download (353kB)| Preview

Abstract

The synthesis of N2-aryl 1,2,3-triazoles from 2,5-disubstituted tetrazoles was achieved under photochemical conditions. This simple and mild one-step reaction provides regiospecific access to 2,4,5-substituted 1,2,3-triazoles via a nitrile imine intermediate. Syntheses of alkyl and heterocylic derivatives were also investigated.

ORCID iDs

Stewart, Sam ORCID: https://orcid.org/0000-0003-3674-5349

Jamieson, Craig ORCID: https://orcid.org/0000-0002-6567-8272

• Share and Export
  

  RDF+XMLBibTeXRIOXX2 XMLRDF+N-TriplesJSONDublin CoreAtomSimple MetadataReferMETSHTML CitationASCII CitationOpenURL ContextObjectEndNoteOpenURL ContextObject in SpanMODSMPEG-21 DIDLEP3 XMLData Cite XMLRIS (EndNote Online, Zotero, Ref manager, etc)RDF+N3Multiline CSV
• Item metadata

  Item type:	Article
  ID code:	51137
  Dates:	Date Event 2014 Published 8 September 2014 Published Online 31 July 2014 Accepted
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	16 Jan 2015 14:53
  Last modified:	11 Nov 2024 10:55
  Related URLs:	Journal or Publication
  URI:	https://strathprints.strath.ac.uk/id/eprint/51137