Soft Scorpionate anions as platforms for novel heterocycles

Rajasekharan Nair, Rajeev and Marckwordt, Annemarie and Lutta, Samuel and Schwalbe, Matthias and Biernat, Anne and Armstrong, David and Watson, Allan and Kennedy, Alan and Reglinski, John and Spicer, Mark (2013) Soft Scorpionate anions as platforms for novel heterocycles. Chemistry - A European Journal, 19 (40). 13561–13568. ISSN 0947-6539 (https://doi.org/10.1002/chem.201300091)

Abstract

Soft scorpionates have thus far been seen mainly as a family of ligands. Their chemistry is extended here to the production of novel cationic macrocycles using dihaloalkanes. By replacing the dihaloalkanes with mild oxidising agents (NO+, I2) we obtain two unique polycyclic heterocycles. The mechanism which leads to the formation of these polycyclic heterocycles is investigated using ab-initio DFT calculations.

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• Item metadata

  Item type:	Article
  ID code:	44096
  Dates:	Date Event 2013 Published
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	18 Jun 2013 08:59
  Last modified:	08 Apr 2024 20:34
  URI:	https://strathprints.strath.ac.uk/id/eprint/44096