A direct and rapid route to α,α-difluoroacylsilanes from trifluoroethanol

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Audouard, Christophe and Garayt, Maxime R and Kerouredan, Erwan and Percy, Jonathan and Yang, Hongli (2005) A direct and rapid route to α,α-difluoroacylsilanes from trifluoroethanol. Journal of Fluorine Chemistry, 126 (4). 609–621. (https://doi.org/10.1016/j.jfluchem.2005.01.005)

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Abstract

α,α-Difluoroacylsilanes were synthesised directly from a range of allyl ethers of trifluoroethanol via dehydrofluorination/metallation procedures, followed by thermal [3,3]-sigmatropic rearrangement of the intermediate vinylmetals. The scope and limitations of ether synthesis and dehydrofluorination/metallation are described.

ORCID iDs

Audouard, Christophe, Garayt, Maxime R, Kerouredan, Erwan, Percy, Jonathan ORCID logoORCID: https://orcid.org/0000-0001-8636-2704 and Yang, Hongli;
CORE (COnnecting REpositories)