A direct and useful route to difluoroacylsilanes and difluoroacylstannanes and their potential for the generation of structurally diverse difluoroketones

Garayt, Maxime R and Percy, Jonathan (2001) A direct and useful route to difluoroacylsilanes and difluoroacylstannanes and their potential for the generation of structurally diverse difluoroketones. Tetrahedron Letters, 42 (36). pp. 6377-6380. ISSN 0040-4039 (https://doi.org/10.1016/S0040-4039(01)01220-5)

Abstract

Allyl trifluoroethyl ethers 2a–2d were prepared; each underwent efficient dehydrofluorination/metallation and trapping to afford a range of difluoroenol silanes and stannanes which rearranged easily and efficiently to the acyl metals. Fluoride-mediated benzylation and allylation of an acylsilane, and Stille coupling of the vinyl- and acyl-stannane were achieved in moderate to good yield.

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• Item metadata

  Item type:	Article
  ID code:	38942
  Dates:	Date Event 2001 Published
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	04 Apr 2012 10:53
  Last modified:	08 Apr 2024 19:53
  URI:	https://strathprints.strath.ac.uk/id/eprint/38942