Split personality of lithium chloride : recent salt effects in organometallic recipes

Hevia, Eva and Mulvey, Robert E. (2011) Split personality of lithium chloride : recent salt effects in organometallic recipes. Angewandte Chemie, 50 (29). pp. 6448-6450. ISSN 0044-8249 (https://doi.org/10.1002/anie.201102054)

Abstract

Jekyll and Hyde: Pinches of LiCl can catalyze orthometalations of halogen-substituted arenes and addition reactions of unsaturated esters, mediated by lithium diisopropylamide. Larger salt portions can transform weak organometallic bases (e.g., Grignard reagents, zincates) into “turbo” reagents of high reactivity and functional group tolerance. But the presence of LiCl, especially as an overlooked metathesis by-product can be detrimental to other catalytic reactions.

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• Item metadata

  Item type:	Article
  ID code:	34744
  Dates:	Date Event 11 July 2011 Published 22 June 2011 Published Online
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	14 Nov 2011 14:04
  Last modified:	08 Apr 2024 19:33
  Related URLs:	Scopus publication
  URI:	https://strathprints.strath.ac.uk/id/eprint/34744