Metal-free α-oxygenation of carbonyl compounds: Methodology and mechanism.

Taylor, Paul H. and Arnott, Euan A. and Tomkinson, Nicholas C. O. (2008) Metal-free α-oxygenation of carbonyl compounds: Methodology and mechanism. In: American Chemical Society , USA, 2011-03-31.

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Abstract

Over the past three years we have described a new family of hydroxylamine reagents which are effective for the α-functionalisation of carbonyl compds. The reactions proceed in one synthetic step using bench stable reagents and can be conducted in the presence of both moisture and air. This poster will describe the broad applicability of this family of hydroxylamine based reagents for the α-functionalisation of carbonyl compds. and disclose our recent findings in unraveling the mechanism of these transformations through a combination of kinetic, synthetic and computational efforts. [on SciFinder(R)]

ORCID iDs

Taylor, Paul H., Arnott, Euan A. and Tomkinson, Nicholas C. O. ORCID logoORCID: https://orcid.org/0000-0002-5509-0133;
  • Item type:Conference or Workshop Item(Other)
    ID code:34170
    Dates:
    Date
    Event
    2008
    Published
    Notes:M1 - Copyright (C) 2011 American Chemical Society (ACS). All Rights Reserved. CAPLUS AN 2008:954713(Conference; Meeting Abstract; Computer Optical Disk)
    Subjects:UNSPECIFIED
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Pure Administrator
    Date deposited:20 Oct 2011 14:17
    Last modified:11 Nov 2024 16:31
    URI:https://strathprints.strath.ac.uk/id/eprint/34170
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