Isolation and structural elucidation of a key aluminoaromatic intermediate and evidence for dismutation phenomena in tmp-alumination chemistry

Conway, B. and Hevia, E. and Garcia-Alvarez, J. and Graham, D.V. and Kennedy, A.R. and Mulvey, R.E. (2007) Isolation and structural elucidation of a key aluminoaromatic intermediate and evidence for dismutation phenomena in tmp-alumination chemistry. Chemical Communications (London) (48). pp. 5241-5243. ISSN 0009-241X (http://dx.doi.org/10.1039/b713913f)

Abstract

Lithium TMP-aluminate iBu3Al(TMP)Li undergoes dismutation in THF solution to precipitate the tetraalkylaluminate [{Li·(THF)4}+{Al(iBu)4}-], but reacts kinetically as a TMP base towards N,N-diisopropylbenzamide to afford the crystalline ortho-aluminated species [(THF)3·Li{O(C)N(iPr)2(C6H4)}Al(iBu)3] and TMPH.

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• Item metadata

  Item type:	Article
  ID code:	17124
  Dates:	Date Event 2007 Published
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Strathprints Administrator
  Date deposited:	17 Apr 2010 11:50
  Last modified:	08 Apr 2024 17:30
  URI:	https://strathprints.strath.ac.uk/id/eprint/17124