The vibrational properties of gold(iii) chloride complexes of bipyridyl and 1,10-phenanthroline

McConnell, A.A. and Brown, D.H. and Smith, W.E. (1982) The vibrational properties of gold(iii) chloride complexes of bipyridyl and 1,10-phenanthroline. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 38 (2). pp. 265-270. ISSN 1386-1425 (http://dx.doi.org/10.1016/0584-8539(82)80206-7)

Abstract

Raman and i.r. spectra of complexes of gold(III) with chloride and bipyridyl or 1,10-phenanthroline ligands are reported. The spectra in both the aromatic-ring stretching region and the metal-halide stretching region are assigned. The compounds are four-coordinate. It is concluded that the nitrogen ligands bridge two AuCl3 moieties in (L2)Au2Cl6 compounds and that bipyridyl AuCl3 is a polymer containing planar bipyridyl AuCl2 units bridged by chloride ions.

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  Item type:	Article
  ID code:	16798
  Dates:	Date Event 1982 Published
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry Faculty of Humanities and Social Sciences (HaSS) > Government and Public Policy > Politics
  Depositing user:	Strathprints Administrator
  Date deposited:	21 Mar 2010 16:19
  Last modified:	11 Nov 2024 09:13
  URI:	https://strathprints.strath.ac.uk/id/eprint/16798