Hydrogen isotope exchange with highly active iridium(I) NHC/phosphine complexes : a comparative counter-ion study
Kerr, William J. and Mudd, Richard J. and Owens, Philippa K. and Reid, Marc and Brown, Jack A. and Campos, Sébastien (2016) Hydrogen isotope exchange with highly active iridium(I) NHC/phosphine complexes : a comparative counter-ion study. Journal of Labelled Compounds and Radiopharmaceuticals, 59 (14). pp. 601-603. ISSN 0362-4803 (https://doi.org/10.1002/jlcr.3427)
Preview |
Text.
Filename: Kerr_etal_JLCR_2016_Hydrogen_isotope_exchange_with_highly_active_iridium_I_NHC_phosphine.pdf
Accepted Author Manuscript Download (715kB)| Preview |
Abstract
Herein we present a range of substrates that undergo hydrogen isotope exchange with an iridium(I) NHC/phosphine complex bearing the less coordinating tetrakis[3,5-bis(trifluoromethyl)phenyl]borate counterion, and compare these with labelling using the equivalent, more established hexafluorophosphate complex. The changes in reactivity and selectivity of these complexes in a series of solvents are examined.
ORCID iDs
Kerr, William J. ORCID: https://orcid.org/0000-0002-1332-785X, Mudd, Richard J. ORCID: https://orcid.org/0000-0001-5786-3745, Owens, Philippa K. ORCID: https://orcid.org/0000-0002-9369-2899, Reid, Marc ORCID: https://orcid.org/0000-0003-4394-3132, Brown, Jack A. and Campos, Sébastien;-
-
Item type: Article ID code: 56684 Dates: DateEvent31 December 2016Published27 July 2016Published Online14 June 2016AcceptedNotes: This is the peer reviewed version of the following article: Kerr, W. J., Mudd, R. J., Owens, P. K., Reid, M., Brown, J. A., and Campos, S. (2016) Hydrogen isotope exchange with highly active iridium(I) NHC/phosphine complexes: a comparative counterion study. J. Label Compd. Radiopharm, doi: 10.1002/jlcr.3427., which has been published in final form at http://dx.doi.org/10.1002/jlcr.3427. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. Subjects: Science > Chemistry Department: Faculty of Science > Pure and Applied Chemistry Depositing user: Pure Administrator Date deposited: 16 Jun 2016 15:24 Last modified: 22 Sep 2024 00:50 Related URLs: URI: https://strathprints.strath.ac.uk/id/eprint/56684