Hydrogen isotope exchange with highly active iridium(I) NHC/phosphine complexes : a comparative counter-ion study

Tools

Kerr, William J. and Mudd, Richard J. and Owens, Philippa K. and Reid, Marc and Brown, Jack A. and Campos, Sébastien (2016) Hydrogen isotope exchange with highly active iridium(I) NHC/phosphine complexes : a comparative counter-ion study. Journal of Labelled Compounds and Radiopharmaceuticals, 59 (14). pp. 601-603. ISSN 0362-4803 (https://doi.org/10.1002/jlcr.3427)

[thumbnail of Kerr-etal-JLCR-2016-Hydrogen-isotope-exchange-with-highly-active-iridium-I-NHC-phosphine]
Preview
 Text. Filename: Kerr_etal_JLCR_2016_Hydrogen_isotope_exchange_with_highly_active_iridium_I_NHC_phosphine.pdf
Accepted Author Manuscript
Download (715kB)| Preview

Abstract

Herein we present a range of substrates that undergo hydrogen isotope exchange with an iridium(I) NHC/phosphine complex bearing the less coordinating tetrakis[3,5-bis(trifluoromethyl)phenyl]borate counterion, and compare these with labelling using the equivalent, more established hexafluorophosphate complex. The changes in reactivity and selectivity of these complexes in a series of solvents are examined.

ORCID iDs

Kerr, William J. ORCID logoORCID: https://orcid.org/0000-0002-1332-785X, Mudd, Richard J. ORCID logoORCID: https://orcid.org/0000-0001-5786-3745, Owens, Philippa K. ORCID logoORCID: https://orcid.org/0000-0002-9369-2899, Reid, Marc ORCID logoORCID: https://orcid.org/0000-0003-4394-3132, Brown, Jack A. and Campos, Sébastien;
  • Item type:Article
    ID code:56684
    Dates:
    Date
    Event
    31 December 2016
    Published
    27 July 2016
    Published Online
    14 June 2016
    Accepted
    Notes:This is the peer reviewed version of the following article: Kerr, W. J., Mudd, R. J., Owens, P. K., Reid, M., Brown, J. A., and Campos, S. (2016) Hydrogen isotope exchange with highly active iridium(I) NHC/phosphine complexes: a comparative counterion study. J. Label Compd. Radiopharm, doi: 10.1002/jlcr.3427., which has been published in final form at http://dx.doi.org/10.1002/jlcr.3427. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Pure Administrator
    Date deposited:16 Jun 2016 15:24
    Last modified:15 Nov 2024 01:08
    Related URLs:
    URI:https://strathprints.strath.ac.uk/id/eprint/56684
CORE (COnnecting REpositories)