Efficient methods for enol phosphate synthesis using carbon-centred magnesium bases
Kerr, William J. and Lindsay, David M. and Patel, Vipulkumar K. and Rajamanickam, Muralikrishnan (2015) Efficient methods for enol phosphate synthesis using carbon-centred magnesium bases. Organic and Biomolecular Chemistry, 13 (40). pp. 10131-10135. ISSN 1477-0520
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Official URL: https://doi.org/10.1039/C5OB01849H
Abstract
Efficient conversion of ketones into kinetic enol phosphates under mild and accessible conditions has been realised using the developed methods with di-tert-butylmagnesium and bismesitylmagnesium. Optimisation of the quench protocol resulted in high yields of enol phosphates from a range of cyclohexanones and aryl methyl ketones, with tolerance of a range of additional functional units.
ORCID iDs
Kerr, William J.


Item type: Article ID code: 54691 Dates: DateEvent21 September 2015Published16 September 2015AcceptedKeywords: ketones, kinetic enol phosphates, cyclohexanones, Chemistry, Chemistry(all) Subjects: Science > Chemistry Department: Faculty of Science > Pure and Applied Chemistry Depositing user: Pure Administrator Date deposited: 11 Dec 2015 01:13 Last modified: 24 Mar 2021 01:32 Related URLs: URI: https://strathprints.strath.ac.uk/id/eprint/54691
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