Regiospecific synthesis of N2-aryl 1,2,3-triazoles from 2,5-disubstituted tetrazoles via photochemically generated nitrile imine intermediates

Stewart, Sam and Harris, Robert and Jamieson, Craig (2014) Regiospecific synthesis of N2-aryl 1,2,3-triazoles from 2,5-disubstituted tetrazoles via photochemically generated nitrile imine intermediates. Synlett, 25 (17). pp. 2480-2484. ISSN 0936-5214 (https://doi.org/10.1055/s-0034-1379010)

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Abstract

The synthesis of N2-aryl 1,2,3-triazoles from 2,5-disubstituted tetrazoles was achieved under photochemical conditions. This simple and mild one-step reaction provides regiospecific access to 2,4,5-substituted 1,2,3-triazoles via a nitrile imine intermediate. Syntheses of alkyl and heterocylic derivatives were also investigated.

ORCID iDs

Stewart, Sam ORCID: https://orcid.org/0000-0003-3674-5349

Jamieson, Craig ORCID: https://orcid.org/0000-0002-6567-8272

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  Item type:	Article
  ID code:	51137
  Dates:	Date Event 2014 Published 8 September 2014 Published Online 31 July 2014 Accepted
  Keywords:	photochemistry, regioselectivity, tetrazole, triazole, indazole, Chemistry, Organic Chemistry
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	16 Jan 2015 14:53
  Last modified:	25 May 2023 09:29
  Related URLs:	Journal or Publication
  URI:	https://strathprints.strath.ac.uk/id/eprint/51137