Z-selective dimerization of aromatic terminal alkynes catalyzed by an iridium(I) n-heterocyclic carbene-phosphine system
Forsyth, Calum and Kerr, William J and Paterson, Laura (2013) Z-selective dimerization of aromatic terminal alkynes catalyzed by an iridium(I) n-heterocyclic carbene-phosphine system. Synlett, 24 (5). pp. 587-590. ISSN 0936-5214
![]()
|
PDF
Kerr_Ir_Cat_Alkyne_Dimerization_Synlett_Published.pdf Final Published Version Download (211kB)| Preview |
Official URL: https://doi.org/10.1055/s-0032-1318271
Abstract
The development of an iridium-catalyzed regio- and stereoselective dimerization process has enabled the formation of (Z)-enyne products. More specifically, low catalyst loadings of an iridium(I) complex, featuring a bulky N-heterocyclic carbene-phosphine ligand combination, has been successfully employed in this selective head-to-head dimerization of terminal alkynes via C-H activation.
Creators(s): |
Forsyth, Calum, Kerr, William J ![]() | Item type: | Article |
---|---|
ID code: | 43134 |
Keywords: | alkynes, enynes, dimerization, C-H activation, iridium, Chemistry, Organic Chemistry |
Subjects: | Science > Chemistry |
Department: | Faculty of Science > Pure and Applied Chemistry |
Depositing user: | Pure Administrator |
Date deposited: | 05 Mar 2013 14:24 |
Last modified: | 25 Dec 2020 01:37 |
Related URLs: | |
URI: | https://strathprints.strath.ac.uk/id/eprint/43134 |
Export data: |
CORE (COnnecting REpositories)