Split personality of lithium chloride : recent salt effects in organometallic recipes
Hevia, Eva and Mulvey, Robert E. (2011) Split personality of lithium chloride : recent salt effects in organometallic recipes. Angewandte Chemie, 50 (29). pp. 6448-6450. ISSN 1521-3773 (https://doi.org/10.1002/anie.201102054)
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Jekyll and Hyde: Pinches of LiCl can catalyze orthometalations of halogen-substituted arenes and addition reactions of unsaturated esters, mediated by lithium diisopropylamide. Larger salt portions can transform weak organometallic bases (e.g., Grignard reagents, zincates) into “turbo” reagents of high reactivity and functional group tolerance. But the presence of LiCl, especially as an overlooked metathesis by-product can be detrimental to other catalytic reactions.
ORCID iDs
Hevia, Eva ORCID: https://orcid.org/0000-0002-3998-7506 and Mulvey, Robert E. ORCID: https://orcid.org/0000-0002-1015-2564;-
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Item type: Article ID code: 34744 Dates: DateEvent11 July 2011Published22 June 2011Published OnlineSubjects: Science > Chemistry Department: Faculty of Science > Pure and Applied Chemistry Depositing user: Pure Administrator Date deposited: 14 Nov 2011 14:04 Last modified: 11 Nov 2024 09:54 Related URLs: URI: https://strathprints.strath.ac.uk/id/eprint/34744
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