Rearrangement strategy for the synthesis of 2-aminoanilines

Porzelle, Achim and Woodrow, Michael D and Tomkinson, Nicholas C. O. (2010) Rearrangement strategy for the synthesis of 2-aminoanilines. Organic Letters, 12 (7). pp. 1492-1495. ISSN 1523-7060

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Official URL: https://doi.org/10.1021/ol100196a

Abstract

Treatment of N-aryl hydroxylamines with trichloroacetonitrile in the presence of Imidazole provides a simple and effective method for the preparation of synthetically versatile 2-aminoanilines. Reactions proceed in DMF at 40 degrees C, providing the products in up to 86% isolated yield.

Creators(s):	Porzelle, Achim, Woodrow, Michael D and Tomkinson, Nicholas C. O. ORCID: https://orcid.org/0000-0002-5509-0133;
Item type:	Article
ID code:	33072
Keywords:	privileged structures, hydroxylamines, chemistry, iodides, Chemistry, Biochemistry, Organic Chemistry, Physical and Theoretical Chemistry
Subjects:	Science > Chemistry
Department:	Faculty of Science > Pure and Applied Chemistry
Depositing user:	Pure Administrator
Date deposited:	30 Aug 2011 12:28
Last modified:	26 May 2020 00:25
URI:	https://strathprints.strath.ac.uk/id/eprint/33072
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