Rearrangement strategy for the synthesis of 2-aminoanilines
Porzelle, Achim and Woodrow, Michael D and Tomkinson, Nicholas C. O. (2010) Rearrangement strategy for the synthesis of 2-aminoanilines. Organic Letters, 12 (7). pp. 1492-1495. ISSN 1523-7060
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Abstract
Treatment of N-aryl hydroxylamines with trichloroacetonitrile in the presence of Imidazole provides a simple and effective method for the preparation of synthetically versatile 2-aminoanilines. Reactions proceed in DMF at 40 degrees C, providing the products in up to 86% isolated yield.
ORCID iDs
Porzelle, Achim, Woodrow, Michael D and Tomkinson, Nicholas C. O.
Item type: Article ID code: 33072 Dates: DateEvent2 April 2010PublishedKeywords: privileged structures, hydroxylamines, chemistry, iodides, Chemistry, Biochemistry, Organic Chemistry, Physical and Theoretical Chemistry Subjects: Science > Chemistry Department: Faculty of Science > Pure and Applied Chemistry Depositing user: Pure Administrator Date deposited: 30 Aug 2011 12:28 Last modified: 26 Mar 2021 03:57 URI: https://strathprints.strath.ac.uk/id/eprint/33072
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