Rearrangement strategy for the synthesis of 2-aminoanilines

Porzelle, Achim and Woodrow, Michael D and Tomkinson, Nicholas C. O. (2010) Rearrangement strategy for the synthesis of 2-aminoanilines. Organic Letters, 12 (7). pp. 1492-1495. ISSN 1523-7060

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Abstract

Treatment of N-aryl hydroxylamines with trichloroacetonitrile in the presence of Imidazole provides a simple and effective method for the preparation of synthetically versatile 2-aminoanilines. Reactions proceed in DMF at 40 degrees C, providing the products in up to 86% isolated yield.

ORCID iDs

Porzelle, Achim, Woodrow, Michael D and Tomkinson, Nicholas C. O. ORCID logoORCID: https://orcid.org/0000-0002-5509-0133;
  • Item type:Article
    ID code:33072
    Dates:
    Date
    Event
    2 April 2010
    Published
    Keywords:privileged structures, hydroxylamines, chemistry, iodides, Chemistry, Biochemistry, Organic Chemistry, Physical and Theoretical Chemistry
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Pure Administrator
    Date deposited:30 Aug 2011 12:28
    Last modified:26 Mar 2021 03:57
    URI:https://strathprints.strath.ac.uk/id/eprint/33072
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