Statistical distribution of binary ligands within rhodium-organic octahedra tunes microporosity in their assemblies

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Tateishi, Tomoki and Troyano, Javier and Tokuda, Shun and Craig, Gavin A and Krause, Simon and López-Olvera, Alfredo and Ibarra, Ilich A and Furukawa, Shuhei (2024) Statistical distribution of binary ligands within rhodium-organic octahedra tunes microporosity in their assemblies. Inorganic Chemistry, 63 (15). pp. 6571-6575. ISSN 1520-510X (https://doi.org/10.1021/acs.inorgchem.4c00964)

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Abstract

Structure-porosity relationships for metal-organic polyhedra (MOPs) are hardly investigated because they tend to be amorphized after activation, which inhibits crystallographic characterization. Here, we show a mixed-ligand strategy to statistically distribute two distinct carbazole-type ligands within rhodium-based octahedral MOPs, leading to systematic tuning of the microporosity in the resulting amorphous solids.

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