Clean-up of divalent cobalt ions by massive sequestration in a low-cost calcium silicate hydrate material

Hamilton, Andrea and Bots, Pieter and Zhou, Han and Liu, Bao and Hall, Christopher (2024) Clean-up of divalent cobalt ions by massive sequestration in a low-cost calcium silicate hydrate material. Scientific Reports, 14 (1). 7052. ISSN 2045-2322 (https://doi.org/10.1038/s41598-024-56617-x)

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Abstract

Cobalt is a critical resource in industrial economies for the manufacture of electric-vehicle batteries, alloys, magnets, and catalysts, but has acute supply-chain risks and poses a threat to the environment. Large-scale sequestration of cobalt in low-cost materials under mild conditions opens a path to cobalt recycling, recovery and environmental clean-up. We describe such sequestration of cobalt by a widely available commercial calcium silicate material containing the mineral xonotlite. Xonotlite rapidly and spontaneously takes up 40 percent of its weight of cobalt under ambient conditions of temperature and pressure and reduces dissolved cobalt concentrations to low parts per million. A new Sharp Front experimental design is used to obtain kinetic and chemical information. Sequestration occurs by a coupled dissolution-precipitation replacement mechanism. The cobalt silicate reaction product is largely amorphous but has phyllosilicate features.

ORCID iDs

Hamilton, Andrea ORCID logoORCID: https://orcid.org/0000-0002-3124-3182, Bots, Pieter ORCID logoORCID: https://orcid.org/0000-0001-6863-0648, Zhou, Han, Liu, Bao and Hall, Christopher;
CORE (COnnecting REpositories)