Structural and magnetic properties of a novel ferrocenyl-diiodine charge transfer complex

Allen, D.W. and Berridge, R. and Bricklebank, N. and Forder, S.D. and Palacio, F. and Coles, S.J. and Hursthouse, M.B. and Skabara, P.J. (2003) Structural and magnetic properties of a novel ferrocenyl-diiodine charge transfer complex. Inorganic Chemistry, 42 (13). pp. 3975-3977. ISSN 1520-510X (http://dx.doi.org/10.1021/ic034092f)

Abstract

The reaction of 4-ferrocenyl-1,3-dithiole-2-thione with diiodine affords an unprecedented 'double' charge-transfer complex; the highly ordered ferrocenium units are held by a supramolecular polyiodide chain, and the material shows evidence of the formation of zigzag magnetic chains below 2 K.

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• Item metadata

  Item type:	Article
  ID code:	830
  Dates:	Date Event 30 June 2003 Published
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Mr Derek Boyle
  Date deposited:	20 Apr 2006
  Last modified:	11 Nov 2024 08:25
  Related URLs:	http://pubs.acs.org/cgi-bin/article.cgi/...
  URI:	https://strathprints.strath.ac.uk/id/eprint/830