Linear conjugated polymer photocatalysts with various linker units for photocatalytic hydrogen evolution from water

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Liu, Lunjie and Kochman, Michał A. and Zhao, Wei and Zwijnenburg, Martijn A. and Sprick, Reiner Sebastian (2022) Linear conjugated polymer photocatalysts with various linker units for photocatalytic hydrogen evolution from water. Chemical Communications, 58 (76). pp. 10639-10642. ISSN 1359-7345 (https://doi.org/10.1039/d2cc03810b)

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Abstract

Polymer photocatalysts have shown potential for light-driven hydrogen evolution from water. Here we studied the relative importance of the linker type in two series of conjugated polymers based on dibenzo[b,d]thiophene sulfone and dimethyl-9H-fluorene. The alkenyl-linked polymers were found to be more active photocatalysts than their alkyl and alkyne-linked counterparts. The co-polymer of dibenzo[b,d]thiophene sulfone and 1,2-diphenylethene has a hydrogen evolution rate of 3334 μmol g−1 h−1 and an external quantum efficiency of 5.6% at 420 nm.

ORCID iDs

Liu, Lunjie, Kochman, Michał A., Zhao, Wei, Zwijnenburg, Martijn A. and Sprick, Reiner Sebastian ORCID logoORCID: https://orcid.org/0000-0002-5389-2706;
  • Item type:Article
    ID code:82450
    Dates:
    Date
    Event
    22 September 2022
    Published
    22 August 2022
    Published Online
    18 August 2022
    Accepted
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Pure Administrator
    Date deposited:22 Sep 2022 15:25
    Last modified:20 Dec 2024 15:11
    URI:https://strathprints.strath.ac.uk/id/eprint/82450
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