A large axial magnetic anisotropy in trigonal bipyramidal Fe(ii)

Hay, Moya A. and Sarkar, Arup and Craig, Gavin A. and Marriott, Katie E. R. and Wilson, Claire and Rajaraman, Gopalan and Murrie, Mark (2020) A large axial magnetic anisotropy in trigonal bipyramidal Fe(ii). Chemical Communications, 56 (50). pp. 6826-6829. ISSN 1359-7345 (https://doi.org/10.1039/D0CC02382E)

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Abstract

The first trigonal bipyramidal Fe(ii) complex to display slow relaxation of magnetisation has been isolated, with this behaviour found to arise through a combination of a large magnetic anisotropy (D = −27.5 cm−1) and a pseudo-D3h symmetry at the Fe(ii) centre, as investigated through ab initio and magnetic studies.

  • Item type:Article
    ID code:72488
    Dates:
    Date
    Event
    25 June 2020
    Published
    6 May 2020
    Published Online
    6 May 2020
    Accepted
    Subjects:Science > Chemistry
    Department:Faculty of Science > Pure and Applied Chemistry
    Depositing user: Pure Administrator
    Date deposited:27 May 2020 15:03
    Last modified:18 Apr 2024 00:27
    URI:https://strathprints.strath.ac.uk/id/eprint/72488
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