Biocatalytic ATRP in solution and on surfaces

Rodriguez, Kyle J. and Pellizzoni, Michela M. and Divandari, Mohammad and Benetti, Edmondo M. and Bruns, Nico; Bruns, Nico and Loos, Katja, eds. (2019) Biocatalytic ATRP in solution and on surfaces. In: Methods in Enzymology. Methods in Enzymology, 627 . Academic Press Inc., Cambridge, MA, pp. 263-290. ISBN 9780128170953 (https://doi.org/10.1016/bs.mie.2019.08.014)

Abstract

The promiscuity of enzymes allows for their implementation as catalysts for non-native chemical transformations. Utilizing the redox activity of metalloenzymes under activator regenerated by electron transfer (ARGET) ATRP conditions, well-controlled and defined polymers can be generated. In this chapter, we review bioATRP in solution and on surfaces and provide experimental protocols for hemoglobin-catalyzed ATRP and for surface-initiated biocatalytic ATRP. This chapter highlights the polymerization of acrylate and acrylamide monomers and provides detailed experimental protocols for the characterization of the polymers and of the polymer brushes.

ORCID iDs

Bruns, Nico ORCID: https://orcid.org/0000-0001-6199-9995

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• Item metadata

  Item type:	Book Section
  ID code:	70455
  Dates:	Date Event 15 October 2019 Published
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	07 Nov 2019 10:46
  Last modified:	18 Dec 2024 11:48
  Related URLs:	Scopus publication
  URI:	https://strathprints.strath.ac.uk/id/eprint/70455