Slow magnetic relaxation in a {CoIICoIII2} complex containing a high magnetic anisotropy trigonal bipyramidal CoII centre

Collet, Alexandra and Craig, Gavin A. and Heras Ojea, María José and Bhaskaran, Lakshmi and Wilson, Claire and Hill, Stephen and Murrie, Mark (2018) Slow magnetic relaxation in a {CoIICoIII2} complex containing a high magnetic anisotropy trigonal bipyramidal CoII centre. Dalton Transactions, 47 (28). pp. 9237-9240. ISSN 1477-9226 (https://doi.org/10.1039/C8DT01997E)

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Abstract

We report a trinuclear mixed-valence {CoIICoIII2} complex, where the CoII centre adopts a trigonal bipyramidal geometry, leading to a large, easy-plane magnetic anisotropy and field-induced slow magnetic relaxation with a Raman-like relaxation process.

ORCID iDs

Collet, Alexandra, Craig, Gavin A., Heras Ojea, María José ORCID logoORCID: https://orcid.org/0000-0002-9290-5178, Bhaskaran, Lakshmi, Wilson, Claire, Hill, Stephen and Murrie, Mark;
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