A topologically unique alternating {CoIII3GdIII3} magnetocaloric ring

Heras Ojea, María José and Lorusso, Giulia and Craig, Gavin A. and Wilson, Claire and Evangelisti, Marco and Murrie, Mark (2017) A topologically unique alternating {CoIII3GdIII3} magnetocaloric ring. Chemical Communications, 53 (35). pp. 4799-4802. ISSN 1359-7345 (https://doi.org/10.1039/C7CC02243C)

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Abstract

The adiabatic temperature change of the star-shaped {CoIII3GdIII3} magnetocaloric ring is enhanced via topological control over the assembly process, by using a pre-formed {CoII(H6L)} building block that undergoes oxidation to CoIII, successfully separating the GdIII ions.

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• Item metadata

  Item type:	Article
  ID code:	69705
  Dates:	Date Event 1 May 2017 Published 13 April 2017 Published Online 5 April 2017 Accepted
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Strathclyde Institute of Pharmacy and Biomedical Sciences Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	09 Sep 2019 14:00
  Last modified:	09 Apr 2024 00:53
  URI:	https://strathprints.strath.ac.uk/id/eprint/69705