Steric effects determine the mechanisms of reactions between bis(N-heterocyclic carbene)-nickel(0) complexes and aryl halides
Nelson, David J. and Maseras, Feliu (2018) Steric effects determine the mechanisms of reactions between bis(N-heterocyclic carbene)-nickel(0) complexes and aryl halides. Chemical Communications. pp. 1-3. ISSN 1359-7345 (In Press)
Preview |
Text.
Filename: Nelson_Maseras_CC2018_Steric_effects_determine_the_mechanisms_of_reactions_between.pdf
Accepted Author Manuscript Download (362kB)| Preview |
Abstract
Computational investigations of the reactions of [Ni(NHC)2] complexes with aryl halides show that the outcomes are governed by the steric impact of the ligand (NHC = N-heterocyclic carbene). Small ligands permit facile oxidative addition, leading to NiII complexes, while larger NHC ligands prevent coordination of the aryl halide and favour the halide abstraction to form NiI.
-
-
Item type: Article ID code: 65391 Dates: DateEvent29 August 2018Published29 August 2018AcceptedSubjects: Science > Chemistry Department: Faculty of Science > Pure and Applied Chemistry Depositing user: Pure Administrator Date deposited: 07 Sep 2018 13:09 Last modified: 17 Apr 2024 00:31 Related URLs: URI: https://strathprints.strath.ac.uk/id/eprint/65391
CORE (COnnecting REpositories)