Soft (S-3-donor) scorpionate complexes of molybdenum and tungsten carbonyls

Garner, M. and Lehmann, M.A. and Reglinski, J. and Spicer, M.D. (2001) Soft (S-3-donor) scorpionate complexes of molybdenum and tungsten carbonyls. Organometallics, 20 (24). pp. 5233-5236. ISSN 0276-7333 (http://dx.doi.org/10.1021/om010559n)

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Abstract

The dicarbonyl(eta (3)-allyl)molybdenum and tri-carbonyliodotungsten complexes with hydrotris(methimazolyl)borate (Tm) are reported as the first examples of transition-metal organometallic complexes of the Tm ligand, serving as general entry points for a wide range of group 6 organometallic complexes. Their crystal structures have been determined, and comparisons are made with the homologous pyrazolylborate (Tp) and cyclopentadienyl (Cp) complexes, leading to predictions regarding their reactions.

ORCID iDs

Garner, M., Lehmann, M.A., Reglinski, J. ORCID logoORCID: https://orcid.org/0000-0002-0263-4168 and Spicer, M.D. ORCID logoORCID: https://orcid.org/0000-0002-6000-5677;
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