Soft (S-3-donor) scorpionate complexes of molybdenum and tungsten carbonyls

Garner, M. and Lehmann, M.A. and Reglinski, J. and Spicer, M.D. (2001) Soft (S-3-donor) scorpionate complexes of molybdenum and tungsten carbonyls. Organometallics, 20 (24). pp. 5233-5236. ISSN 0276-7333 (http://dx.doi.org/10.1021/om010559n)

Abstract

The dicarbonyl(eta (3)-allyl)molybdenum and tri-carbonyliodotungsten complexes with hydrotris(methimazolyl)borate (Tm) are reported as the first examples of transition-metal organometallic complexes of the Tm ligand, serving as general entry points for a wide range of group 6 organometallic complexes. Their crystal structures have been determined, and comparisons are made with the homologous pyrazolylborate (Tp) and cyclopentadienyl (Cp) complexes, leading to predictions regarding their reactions.

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• Item metadata

  Item type:	Article
  ID code:	556
  Dates:	Date Event 26 November 2001 Published
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Mr Derek Boyle
  Date deposited:	20 Mar 2006
  Last modified:	08 Apr 2024 15:21
  Related URLs:	http://pubs.acs.org/cgi-bin/article.cgi/...
  URI:	https://strathprints.strath.ac.uk/id/eprint/556