CO2 fixation employing an iridium(i)-hydroxide complex

Truscott, Byron J. and Nelson, David J. and Slawin, Alexandra M Z and Nolan, Steven P. (2014) CO2 fixation employing an iridium(i)-hydroxide complex. Chemical Communications, 50 (3). pp. 286-288. ISSN 1359-7345 (https://doi.org/10.1039/c3cc46922k)

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Abstract

The reactivity of a number of IrI complexes towards CO 2 is explored using [Ir(NHC)(OH)] as a key synthon. CO2 insertion into Ir-O and Ir-N bonds proved facile, yielding a number of Ir I-carbonates and -carbamates. Most importantly, reaction between CO2 and IrI-OH led to isolation of the novel [{Ir I}2-(μ-κ1:κ2-CO 3)] complex.

  • Item type:Article
    ID code:47846
    Dates:
    Date
    Event
    11 January 2014
    Published
    Subjects:Science > Chemistry
    Department:UNSPECIFIED
    Depositing user: Pure Administrator
    Date deposited:06 May 2014 14:50
    Last modified:08 Apr 2024 21:29
    Related URLs:
    URI:https://strathprints.strath.ac.uk/id/eprint/47846
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