14-Bromo-12-chloro-2,16-dioxapentacyclohenicosa-3(8),10,12,14-tetraene-7,20-dione

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Kennedy, Alan and Akkurt, Mehmet and Mohamed, Shaaban K and Andelhamid, AA and marzouk, AAE (2013) 14-Bromo-12-chloro-2,16-dioxapentacyclohenicosa-3(8),10,12,14-tetraene-7,20-dione. Acta Crystallographica Section E: Structure Reports, 69. o769-o770. ISSN 1600-5368 (https://doi.org/10.1107/S1600536813010374)

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Abstract

In the title compound, C19H16BrClO4, both the fused xanthene rings and one of the cyclohexane rings adopt envelope conformations, while the other cyclohexane ring is in a chair conformation. In the crystal, molecules are linked by C-H...O hydrogen bonds, forming infinite chains running along [10-1] incorporating R22(16) ring motifs. In addition, C-H...[pi] interactions and weak [pi]-[pi] stacking interactions [centroid-centroid distance = 3.768 (3) Å] help to consolidate the packing.

ORCID iDs

Kennedy, Alan ORCID logoORCID: https://orcid.org/0000-0003-3652-6015, Akkurt, Mehmet, Mohamed, Shaaban K, Andelhamid, AA and marzouk, AAE;
CORE (COnnecting REpositories)