Regioselective heterohalogenation of 4-halo-anisoles via a series of sequential ortho-aluminations and electrophilic halogenations

Conway, Benjamin Grant and Crosbie, Elaine and Kennedy, Alan and Mulvey, Robert E. and Robertson, Stuart D. (2012) Regioselective heterohalogenation of 4-halo-anisoles via a series of sequential ortho-aluminations and electrophilic halogenations. Chemical Communications, 48 (39). pp. 4674-4676. ISSN 1359-7345 (https://doi.org/10.1039/c2cc30795b)

Abstract

As the aluminate base [LiAl(TMP)(2)(iBu)(2)] 1 displays halogen tolerance towards substituted aromatics, 4-halo-anisoles have been ortho-aluminated and electrophilically quenched to form synthetically useful multi-heterohalogenated anisoles, with the Al intermediates along the route structurally defined.

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• Item metadata

  Item type:	Article
  ID code:	39817
  Dates:	Date Event 2012 Published
  Subjects:	Science > Chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Pure Administrator
  Date deposited:	29 May 2012 09:32
  Last modified:	08 Apr 2024 19:56
  Related URLs:	Scopus publication
  URI:	https://strathprints.strath.ac.uk/id/eprint/39817